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Reactions: Acetylene Preparation of acetylene and the reaction of chlorine with acetylene are demonstrated. An antique carbide lamp is also demonstrated.
A Simple Method for Drawing Chiral Mononuclear Octahedral Metal ComplexesAminou Mohamadou and Arnaud Haudrechy This article presents a simple and progressive method to draw all of the octahedral complexes of coordination units with at least two different monodentate ligands and show their chiral properties. Mohamadou, Aminou; Haudrechy, Arnaud. J. Chem. Educ.2008, 85, 436.
Asymmetric Synthesis |
Chirality / Optical Activity |
Coordination Compounds |
Diastereomers |
Enantiomers |
Molecular Properties / Structure |
Stereochemistry |
Transition Elements
Hydration of Acetylene: A 125th AnniversaryDmitry A. Ponomarev and Sergey M. Shevchenko The discovery the hydration of alkynes catalyzed by mercury ions by Mikhail Kucherov made possible industrial production of acetaldehyde from acetylene and had a profound effect on the development of industrial chemistry in the 1920th centuries. Ponomarev, Dmitry A.; Shevchenko, Sergey M. J. Chem. Educ.2007, 84, 1725.
Addition Reactions |
Aldehydes / Ketones |
Alkynes |
Catalysis |
Industrial Chemistry |
Reactions
The Aromaticity of Pericyclic Reaction Transition StatesHenry S. Rzepa Presents an approach that combines two fundamental concepts in organic chemistry, chirality and aromaticity, into a simple rule for stating selection rules for pericyclic reactions in terms of achiral Hckel-aromatic and chiral Mbius-aromatic transition states. Rzepa, Henry S. J. Chem. Educ.2007, 84, 1535.
Unsaturated HydrocarbonsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alkenes |
Alkynes
Orbital Descriptions of Multiple BondsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
