12.10. Molecular Structure: Molecules with Double Bonds
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Exploring Solid-State Structure and Physical Properties: A Molecular and Crystal Model ExerciseThomas H. Bindel This laboratory allows students to examine relationships among the microscopicmacroscopicsymbolic levels using crystalline mineral samples and corresponding crystal models. The exercise also reinforces Lewis dot structures, VSEPR theory, and the identification of molecular and coordination geometries. Bindel, Thomas H. J. Chem. Educ.2008, 85, 822.
Crystals / Crystallography |
Molecular Properties / Structure |
Molecular Modeling |
Solids |
VSEPR Theory |
Lewis Structures |
Physical Properties
Teaching Molecular Geometry with the VSEPR ModelRonald J. Gillespie The difficulties associated with the usual treatment of the VB and MO theories in connection with molecular geometry in beginning courses are discussed. It is recommended that the VB and MO theories should be presented only after the VSEPR model either in the general chemistry course or in a following course, particularly in the case of the MO theory, which is not really necessary for the first-year course. Gillespie, Ronald J. J. Chem. Educ.2004, 81, 298.
Covalent Bonding |
Molecular Properties / Structure |
Main-Group Elements |
Theoretical Chemistry |
VSEPR Theory |
MO Theory
Multiple bonds and the VSEPR modelGillespie, Ronald J. The purpose of this paper is to review the application of the VSEPR model to molecules containing multiple bonds and to compare the usefulness and applicability of the model to other models for multiple bonds. Gillespie, Ronald J. J. Chem. Educ.1992, 69, 116.