The Visible and Ultraviolet Spectra of Molecules: Molecular Orbitals
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The Fuge Tube Diode Array SpectrophotometerB. T. Arneson, S. R. Long, K. K. Stewart, and J. J. Lagowski Presents details for adapting a diode array UVvis spectrophotometer to incorporate the use of polypropylene microcentrifuge tubesfuge tubesas cuvettes. The fuge tubes also can serve as reaction vessels, which permits the ready study of chemical systems involving heterogeneous phases by eliminating the need for tedious separations. Arneson, B. T.; Long, S. R.; Stewart, K. K.; Lagowski, J. J. J. Chem. Educ.2008, 85, 1663.
Laboratory Equipment / Apparatus |
Solutions / Solvents |
Spectroscopy |
UV-Vis Spectroscopy
Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) ComplexesRichard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction. Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ.2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
Resolving Spectral Lines with a Periscope-Type DVD SpectroscopeFumitaka Wakabayashi Describes the periscope-type of DVD spectroscope and demonstrates the numerical analysis of its emission and absorption spectra. This improved design allows one to observe and photograph visible spectra more easily and clearly than earlier models; it thus has the potential to be a cost-effective, powerful, and versatile tool for science education. Wakabayashi, Fumitaka. J. Chem. Educ.2008, 85, 849.
Spectrophotometer, Scanning UV-Visible (ChemPages Lab)John W. Moore, Jerrold J. Jacobsen, Joe L. March Spectrophotometer, Scanning UV/Visible: this is a resource in the collection "ChemPages Laboratory Resources". A scanning ultraviolet/visible (UV/Vis) spectrophotometer operates on the same principles as a Spectronic 20?. They both can be used for qualitative and quantitative analysis. The ChemPages Laboratory Resources are a set of web pages that include text, images, video, and self check questions. The topics included are those that are commonly encountered in the first-year chemistry laboratory. They have been put together for use as both a pre-laboratory preparation tool and an in-laboratory reference source.
UV-Vis Spectroscopy |
Laboratory Equipment / Apparatus
Spectrometer, Spectronic 20 (ChemPages Lab)John W. Moore, Jerrold J. Jacobsen, Joe L. March Spectrometer, Spectronic 20?: this is a resource in the collection "ChemPages Laboratory Resources". The Spectronic 20? is used to measure the absorbance (or transmittance) of solutions. A Spectronic 20? is capable of measuring % transmittance and absorbance over the range of 340 to 950 nm (the range 600 to 950 nm requires a special infrared filter and a different lamp). The ChemPages Laboratory Resources are a set of web pages that include text, images, video, and self check questions. The topics included are those that are commonly encountered in the first-year chemistry laboratory. They have been put together for use as both a pre-laboratory preparation tool and an in-laboratory reference source.