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Electrochemical Series: Metal Trees A piece of metal (Cu, Zn, Ag, Cd, or Pb) is placed in an aqueous solution of a metal ion (Cu2+, Zn2+, Ag+, Cd2+, or Pb2+). In some cases the growth of metal crystals indicates that a chemical reaction has occurred.
Consider the electrochemical cell diagram shown below. As you observe the reaction in the cell, you notice that the tin electrode seems to be disappearing while there are deposits forming on the silver electrode. Which of the following is a correct statement?
Textbook Error: Short Circuiting an Electrochemical CellJudith M. Bonicamp and Roy W. Clark Reports a serious error in the electrochemical diagrams in eight, 21st century texts and offers an analogy to electrical potential energy and a diagram to clarify the interrelationships between electromotive force E, reaction quotient Q, and Gibbs free energy G. Bonicamp, Judith M.; Clark, Roy W. J. Chem. Educ.2007, 84, 731.
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials
A Direct Methanol Fuel CellOrfeo Zerbinati Materials and methods for construction of a direct methanol fuel cell. Zerbinati, Orfeo. J. Chem. Educ.2002, 79, 829.
Electromotive Force of Galvanic CellsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Electrolytic / Galvanic Cells / Potentials
Galvanic CellsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Electrolytic / Galvanic Cells / Potentials
Galvanic Cells and Free EnergyEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Zn2+(aq) + 2e- 
