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Overvoltage Zinc metal reacts with hydrochloric acid, generating hydrogen gas. However, when a strip of nickel, copper, platinum or lead is placed in hydrochloric acid, no reaction is observed.
The Electrochemical Synthesis of Transition-Metal AcetylacetonatesS. R. Long, S. R. Browning, and J. J. Lagowski The electrochemical synthesis of transition-metal acetylacetonates can assist in the transformation of an entry-level laboratory course into a research-like environment where all members of a class are working on the same problem, but each student has a personal responsibility for the synthesis and characterization of a specific compound. Long, S. R.; Browning, S. R.; Lagowski, J. J. J. Chem. Educ.2008, 85, 1429.
Coordination Compounds |
Electrochemistry |
IR Spectroscopy |
Physical Properties |
Synthesis |
Transition Elements |
UV-Vis Spectroscopy
New Observations on the Copper-to-Silver-to-Gold DemonstrationDorin Bejan, Jeff Hastie, and Nigel J. Bunce This analysis of the classic copper-to-silver-to-gold demonstration describes the deposition of zinc in the form of the silver-colored alloy ?-brass, the evolution of hydrogen at the copper cathode, and the behavior of the associated electrochemical cell. Bejan, Dorin; Hastie, Jeff; Bunce, Nigel J. J. Chem. Educ.2008, 85, 1381.
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials |
Oxidation State |
Oxidation / Reduction
Introducing Undergraduate Students to Electrochemistry: A Two-Week Discovery Chemistry ExperimentKenneth V. Mills, Richard S. Herrick, Louise W. Guilmette, Lisa P. Nestor, Heather Shafer, and Mauri A. Ditzler, Within the framework of a laboratory-focused, guided-inquiry pedagogy, students discover the Nernst equation, the spontaneity of galvanic cells, concentration cells, and the use of electrochemical data to calculate equilibrium constants. Mills, Kenneth V.; Herrick, Richard S.; Guilmette, Louise W.; Nestor, Lisa P.; Shafer, Heather;Ditzler, Mauri A. J. Chem. Educ.2008, 85, 1116.
Refining of CopperEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Industrial Chemistry |
Electrochemistry
ChemPaths 104 M Apr 25John W. Moore Today in Chem 104:
* Lecture: Electrochemistry; Redox; Electrochemical Cells
* Reading:
Kotz: Ch. 20, Sec. 1-2
Moore: Ch. 19, Sec. 1-2
* Homework #11 due by 11:55 PM F Apr 29
* Quiz in second discussion section this week
* Lab this week is #9, Copper Ammine Compounds
Electrochemistry
ChemPaths 104 W Apr 27John W. Moore Today in Chem 104:
* Lecture: Electrochemistry; Redox; Electrochemical Cells
* Reading:
Kotz: Ch. 20, Sec. 3-4
Moore: Ch. 19, Sec. 3-5
* Homework #11 due by 11:55 PM F Apr 29
* Quiz in second discussion section this week
* Lab this week is #9, Copper Ammine Compounds
Go for the oxidation of 2 mole of silver in the following balanced reaction. 
Ca(s) + 2AgI(s) 
