14.5. Preparation of 2-Chloro-2-Methylbutane: An SN1 Reaction
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Nucleophilic Substitution Reactions Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Chart for Deciding Mechanism for Reaction of Alkyl Halide with Nucleophile/BaseMcClelland, Bruce W. The decision chart offered here is based upon the well-known and accepted characteristics of the reaction system mechanisms described in typical introductory organic chemistry textbooks. McClelland, Bruce W. J. Chem. Educ.1994, 71, 1047.
Hydrolysis of benzenediazonium ionSheats, John E.; Harbison, Kenneth G. Presents a more convenient approach to studying the kinetics of the hydrolysis of benzenediazonium ion. Sheats, John E.; Harbison, Kenneth G. J. Chem. Educ.1970, 47, 779.
