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1 Videos
3 Assessment Questions
85 Journal Articles
Videos: 1 results
Nucleophilic Substitution Reactions  
Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Nucleophilic Substitution
Assessment Questions: 3 results
Substitution and Elimination (6 Variations)
A collection of 6 assessment questions about Substitution and Elimination
Mechanisms of Reactions |
Nucleophilic Substitution |
Elimination Reactions |
Carbocations |
Stereochemistry |
Alcohols |
Ethers
Nucleophilic Substitution (18 Variations)
A collection of 18 assessment questions about Nucleophilic Substitution
Nucleophilic Substitution |
Carbocations |
Alcohols |
Stereochemistry |
Epoxides |
Ethers
Aldol Reactions (30 Variations)
A collection of 30 assessment questions about Aldol Reactions
Aldehydes / Ketones |
Esters |
Amides |
Carboxylic Acids |
Mechanisms of Reactions |
Acids / Bases |
Reactions |
Synthesis |
Elimination Reactions |
Resonance Theory
Journal Articles: First 3 results.
Pedagogies:
Frank Westheimer's Early Demonstration of Enzymatic Specificity  Addison Ault
Reviews one of the most significant accomplishments of one of the most respected chemists of the 20th centurya series of stereospecific enzymatic oxidation and reduction experiments that led chemists to recognize enantiotopic and diastereotopic relationships of atoms, or groups of atoms, within molecules.
Ault, Addison. J. Chem. Educ. 2008, 85, 1246.
Asymmetric Synthesis |
Bioorganic Chemistry |
Catalysis |
Chirality / Optical Activity |
Enantiomers |
Enzymes |
Isotopes |
Nucleophilic Substitution |
Oxidation / Reduction |
Stereochemistry
Polymer-Supported Reagents and 1H–19F NMR Couplings: The Synthesis of 2-Fluoroacetophenone  Nicola Pohl and Kimberly Schwarz
Describes an experiment in which 2-bromoacetophenone is converted to 2-fluoroacetophenone using a solid-phase nucleophilic fluorine source. The experiment introduces students to the utility of solid-phase reagents in organic synthesis, to NMR-active nuclei other than 1H without the requirement of a special NMR probe, and to the unique uses of fluorine in molecular design.
Pohl, Nicola; Schwarz, Kimberly. J. Chem. Educ. 2008, 85, 834.
Aldehydes / Ketones |
NMR Spectroscopy |
Nucleophilic Substitution |
Synthesis
Pyrolysis of Aryl Sulfonate Esters in the Absence of Solvent: E1 or E2? A Puzzle for the Organic Laboratory  John J. Nash, Marnie A. Leininger, and Kurt Keyes
An aryl sulfonate ester is synthesized and then pyrolyzed at reduced pressure. The volatile products are analyzed using gas chromatography to determine whether the thermal decomposition occurs via an E1 or E2 mechanism.
Nash, John J.; Leininger, Marnie A.; Keyes, Kurt . J. Chem. Educ. 2008, 85, 552.
Alkenes |
Carbocations |
Elimination Reactions |
Gas Chromatography |
Mechanisms of Reactions |
Synthesis
View all 85 articles