14.2. Classification of Nucleophilic Substitution Reactions
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Nucleophilic Substitution Reactions Solvolysis of secondary versus tertiary halides, effects of leaving groups, solvolysis of/and reactions of sodium iodide and silver nitrate with isomers of bromobutane, SN1 and SN2 mechanisms, and hydrolysis of tert-butyl chloride are demonstrated.
Chart for Deciding Mechanism for Reaction of Alkyl Halide with Nucleophile/BaseMcClelland, Bruce W. The decision chart offered here is based upon the well-known and accepted characteristics of the reaction system mechanisms described in typical introductory organic chemistry textbooks. McClelland, Bruce W. J. Chem. Educ.1994, 71, 1047.
Mechanisms of Reactions |
Nucleophilic Substitution
Two working models for the SN2 mechanismAnderson, Martin M. Design of an articulated physical model demonstrating the mechanism of the SN2 reaction. Anderson, Martin M. J. Chem. Educ.1987, 64, 1023.
