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Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different ConceptsGerard Parkin The purpose of this article is to clarify the terms valence, oxidation number, coordination number, formal charge, and number of bonds and illustrate how the valence of an atom in a molecule provides a much more meaningful criterion for establishing the chemical reasonableness of a molecule than does the oxidation number. Parkin, Gerard. J. Chem. Educ.2006, 83, 791.
Coordination Compounds |
Covalent Bonding |
Lewis Structures |
Oxidation State |
Nomenclature / Units / Symbols
The Discovery and Development of CisplatinRebecca A. Alderden, Matthew D. Hall, and Trevor W. Hambley Cisplatin is currently one of the most widely used anticancer drugs in the world. The unlikely events surrounding the discovery of its anticancer activity, subsequent introduction into the clinic, and the continuing research into platinum compounds is the subject of this review. Alderden, Rebecca A.; Hall, Matthew D.; Hambley, Trevor W. J. Chem. Educ.2006, 83, 728.
Interactive Pi Bonding EffectsWilliam F. Coleman This application demonstrates the effect of pi bonding on the one-electron ligand field splitting in an octahedral. By clicking on the appropriate buttons students can see how D changes when you move from ligands with no pi bonding capability to pi donor and pi acceptor ligands.
Covalent Bonding |
Crystal Field / Ligand Field Theory |
Coordination Compounds |
Enrichment / Review Materials
Coordination CompoundsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Coordination Compounds
Geometry of ComplexesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.