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Introducing Undergraduate Students to Electrochemistry: A Two-Week Discovery Chemistry ExperimentKenneth V. Mills, Richard S. Herrick, Louise W. Guilmette, Lisa P. Nestor, Heather Shafer, and Mauri A. Ditzler, Within the framework of a laboratory-focused, guided-inquiry pedagogy, students discover the Nernst equation, the spontaneity of galvanic cells, concentration cells, and the use of electrochemical data to calculate equilibrium constants. Mills, Kenneth V.; Herrick, Richard S.; Guilmette, Louise W.; Nestor, Lisa P.; Shafer, Heather;Ditzler, Mauri A. J. Chem. Educ.2008, 85, 1116.
Electrochemistry |
Electrolytic / Galvanic Cells / Potentials |
Equilibrium
The Use of Conjugate Charts in Transfer Reactions: A Unified ApproachMichael I. Allnutt Redox reactions are discussed in terms of the relative strengths of the oxidant, the reductant, and their conjugates; a conjugate chart is a convenient and useful way of doing this. A similar chart for acids and bases that can be applied in the same manner is proposed. Allnutt, Michael I. J. Chem. Educ.2007, 84, 1659.
Acids / Bases |
Electrolytic / Galvanic Cells / Potentials |
Oxidation / Reduction |
Brønsted-Lowry Acids / Bases
Redox Titration of Ferricyanide to Ferrocyanide with Ascorbic Acid: Illustrating the Nernst Equation and Beer–Lambert LawTina H. Huang, Gail Salter, Sarah L. Kahn, and Yvonne M. Gindt In this simple experiment, which illustrates the Nernst equation and BeerLambert law, students monitor the reduction of ferricyanide ion to ferrocyanide electrochemically and spectrophoto-metrically upon titration with ascorbic acid. The Nernst equation is used to calculate the standard reduction potential of the redox couple at pH 7 and the number of electrons transferred. Huang, Tina H.; Salter, Gail; Kahn, Sarah L.; Gindt, Yvonne M. J. Chem. Educ.2007, 84, 1461.
ElectrolysisEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Electrochemistry |
Oxidation / Reduction
Chromate-Dichromate (GCMP)David M. Whisnant Chromate/Dichromate: this is a resource in the collection "General Chemistry Multimedia Problems". In this problem we will study shifts in the equilibrium between chromate and dichromate. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Oxidation / Reduction
Halogens and Halides (GCMP)David M. Whisnant Halogens and Halides: this is a resource in the collection "General Chemistry Multimedia Problems". In this problem we will study the oxidation-reduction reactions between the halogens and the halide ions. The halogens and halides will be dissolved in water and hexane. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Go for the oxidation of 2 mole of silver in the following balanced reaction. 
Ca(s) + 2AgI(s) 
