12.10 From Alcohols to Aldehydes, Ketones and Carboxylic Acids
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Aldehydes and Ketones Addition of bisulfite to cyclohexanone, 2,4-dirntrohelyhydazine test for carbonyl compounds, iodoform test, Tollens test, oxidation of ascorbic acid, aldol condensation, and ketene generator are demonstrated.
Carboxylic Acids and Derivatives Conductivity of carboxylic acids, pH of acetic acid derivatives, hydrophobic effect, and soap emulsions of hydrocarbons are demonstrated.
Organic : FunctionalGroups (18 Variations) The structure for niacin (one of the B-vitamins) is shown below. Which of the following functional groups is present in niacin?
The Glyoxal Clock ReactionJulie B. Ealy, Alexandra Rodriguez Negron, Jessica Stephens, Rebecca Stauffer, and Stanley D. Furrow The glyoxal clock reaction has been adapted to a general chemistry kinetics lab to determine the order of the reacting species using a Calculator Based Laboratory or LabPro equipment. Ealy, Julie B.; Negron, Alexandra Rodriguez; Stephens, Jessica; Stauffer, Rebecca; Furrow, Stanley D. J. Chem. Educ.2007, 84, 1965.
Aldehydes / Ketones |
Dyes / Pigments |
Kinetics |
Lewis Acids / Bases |
Mechanisms of Reactions |
Rate Law |
Reactions
Hydration of Acetylene: A 125th AnniversaryDmitry A. Ponomarev and Sergey M. Shevchenko The discovery the hydration of alkynes catalyzed by mercury ions by Mikhail Kucherov made possible industrial production of acetaldehyde from acetylene and had a profound effect on the development of industrial chemistry in the 1920th centuries. Ponomarev, Dmitry A.; Shevchenko, Sergey M. J. Chem. Educ.2007, 84, 1725.
ChemPaths 104 M Jan 24John W. Moore Today in Chem 104:
* Lecture: Organic Chemistry
* Reading:
Kotz: Ch. 10, Sec. 3-4
Moore: Ch. 12: Sec. 1, 3-4
* Practice Quiz, Homework #1 due by 11:55pm Today!
* Also, Safety Quiz is due before lab this week.
Alcohols |
Ethers |
Aldehydes / Ketones |
Carboxylic Acids |
Amines / Ammonium Compounds
Aldehydes and KetonesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.