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Alcohols Oxidation of alcohols with chromic acid, oxidation of glycerin with potassium permanganate, Lucas test, ethanol cannon, and construction of a baster ball cannon are demonstrated.
Phenols and Quinones Ferric chloride test for phenols, nitration of acetaminophen, extraction of dichloroindophenol, oxidation of phenols with sodium periodate, nucleophilic addition to quinones, "purple benzene", oxidation of 2,6-Dit-butlhydoquinone, decolorization of crystal violet, and chameleon emulsion are demonstrated.
Entropy and the Shelf Model: A Quantum Physical Approach to a Physical PropertyArnd H. Jungermann A quantum physical approach relying on energy quantization leads to three simple rules which are the key to understanding the physical property described by molar entropy values. Jungermann, Arnd H. J. Chem. Educ.2006, 83, 1686.
Alcohols |
Alkanes / Cycloalkanes |
Carboxylic Acids |
Covalent Bonding |
Ionic Bonding |
Physical Properties |
Quantum Chemistry |
Thermodynamics
Equilibrium Constants and Water Activity RevisitedDavid Keeports Subtle arguments based upon the use of chemical potentials show that numerical values of solute molar concentrations can be used as good approximate activities in equilibrium calculations for reactions involving dilute solutions. Keeports, David. J. Chem. Educ.2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
Equilibrium Constants and Water Activity RevisitedE. J. Behrman In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols. Behrman, E. J. J. Chem. Educ.2006, 83, 1290.
AlcoholsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Alcohols |
Addition Reactions
ChemPaths 104 M Jan 24John W. Moore Today in Chem 104:
* Lecture: Organic Chemistry
* Reading:
Kotz: Ch. 10, Sec. 3-4
Moore: Ch. 12: Sec. 1, 3-4
* Practice Quiz, Homework #1 due by 11:55pm Today!
* Also, Safety Quiz is due before lab this week.