| Journal Articles: 76 results |
|
|
A New "Bottom-Up" Framework for Teaching Chemical Bonding Tami Levy Nahum, Rachel Mamlok-Naaman, Avi Hofstein, and Leeor Kronik This article presents a general framework for bonding that can be presented at different levels of sophistication depending on the student's level and needs. The pedagogical strategy for teaching this model is a "bottom-up" one, starting with basic principles and ending with specific properties. Levy Nahum, Tami; Mamlok-Naaman, Rachel; Hofstein, Avi; Kronik, Leeor. J. Chem. Educ. 2008, 85, 1680.
Atomic Properties / Structure |
Covalent Bonding |
Ionic Bonding |
Lewis Structures |
Materials Science |
MO Theory |
Noncovalent Interactions
|
The Mechanism of Covalent Bonding: Analysis within the Hückel Model of Electronic Structure Sture Nordholm, Andreas Bäck, and George B. Bacskay Hckel molecular orbital theory is shown to be uniquely useful in understanding and interpreting the mechanism of covalent bonding. Using the Hckel model it can be demonstrated that the dynamical character of the molecular orbitals is related simultaneously to the covalent bonding mechanism and to the degree of delocalization of the electron dynamics. Nordholm, Sture; Bäck, Andreas; Bacskay, George B. J. Chem. Educ. 2007, 84, 1201.
Covalent Bonding |
MO Theory |
Quantum Chemistry |
Theoretical Chemistry
|
Predicting the Stability of Hypervalent Molecules Tracy A. Mitchell, Debbie Finocchio, and Jeremy Kua In this exercise, students use concepts in thermochemistry such as bond energy, ionization potentials, and electron affinities to predict the relative stability of two hypervalent molecules (PF5 and PH5) relative to their respective non-hypervalent counterparts. Mitchell, Tracy A.; Finocchio, Debbie; Kua, Jeremy. J. Chem. Educ. 2007, 84, 629.
Computational Chemistry |
Covalent Bonding |
Ionic Bonding |
Lewis Structures |
Molecular Modeling |
Calorimetry / Thermochemistry |
Molecular Properties / Structure
|
Let Us Give Lewis Acid–Base Theory the Priority It Deserves Alan A. Shaffer The Lewis concept is simple yet powerful in its scope, and can be used to help beginning students understand reaction mechanisms more fully. However, traditional approaches to acid-base reactions at the introductory level ignores Lewis acid-base theory completely, focusing instead on proton transfer described by the Br?nsted-Lowry concept. Shaffer, Alan A. J. Chem. Educ. 2006, 83, 1746.
Acids / Bases |
Lewis Acids / Bases |
Lewis Structures |
Mechanisms of Reactions |
Molecular Properties / Structure |
VSEPR Theory |
Covalent Bonding |
Brønsted-Lowry Acids / Bases
|
Entropy and the Shelf Model: A Quantum Physical Approach to a Physical Property Arnd H. Jungermann A quantum physical approach relying on energy quantization leads to three simple rules which are the key to understanding the physical property described by molar entropy values. Jungermann, Arnd H. J. Chem. Educ. 2006, 83, 1686.
Alcohols |
Alkanes / Cycloalkanes |
Carboxylic Acids |
Covalent Bonding |
Ionic Bonding |
Physical Properties |
Quantum Chemistry |
Thermodynamics
|
More on the Nature of Resonance Robert C. Kerber The author continues to find the use of delocalization preferable to resonance. Kerber, Robert C. . J. Chem. Educ. 2006, 83, 1291.
Aromatic Compounds |
Covalent Bonding |
Molecular Properties / Structure |
Resonance Theory |
Nomenclature / Units / Symbols
|
More on the Nature of Resonance William B. Jensen Supplements a recent article on the interpretation of resonance theory with three additional observationsone historical and two conceptual. Jensen, William B. J. Chem. Educ. 2006, 83, 1290.
Aromatic Compounds |
Covalent Bonding |
Molecular Properties / Structure |
Nomenclature / Units / Symbols |
Resonance Theory
|
Valence, Oxidation Number, and Formal Charge: Three Related but Fundamentally Different Concepts Gerard Parkin The purpose of this article is to clarify the terms valence, oxidation number, coordination number, formal charge, and number of bonds and illustrate how the valence of an atom in a molecule provides a much more meaningful criterion for establishing the chemical reasonableness of a molecule than does the oxidation number. Parkin, Gerard. J. Chem. Educ. 2006, 83, 791.
Coordination Compounds |
Covalent Bonding |
Lewis Structures |
Oxidation State |
Nomenclature / Units / Symbols
|
If It's Resonance, What Is Resonating? Robert C. Kerber This article reviews the origin of the terminology associated with the use of more than one Lewis-type structure to describe delocalized bonding in molecules and how the original usage has evolved to reduce confusion Kerber, Robert C. . J. Chem. Educ. 2006, 83, 223.
Aromatic Compounds |
Covalent Bonding |
Molecular Properties / Structure |
Nomenclature / Units / Symbols |
Resonance Theory
|
The Nature of Hydrogen Bonding Emeric Schultz Students use toy connecting blocks and Velcro to investigate weak intermolecular interactions, specifically hydrogen bonds. Schultz, Emeric. J. Chem. Educ. 2005, 82, 400A.
Noncovalent Interactions |
Hydrogen Bonding |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Covalent Bonding |
Molecular Modeling |
Molecular Properties / Structure
|
Valence, Covalence, Hypervalence, Oxidation State, and Coordination Number Derek W. Smith It is argued that the terms valence, covalence, hypervalence, oxidation state, and coordination number are often confused and misused in the literature. It is recommended that use of the term valence, and its associated terminology, should be restricted to simple molecular main group substances and to some oxoacids and derivatives, but avoided in both main group and transition element coordination chemistry. Smith, Derek W. J. Chem. Educ. 2005, 82, 1202.
Coordination Compounds |
Covalent Bonding |
Main-Group Elements |
Oxidation State
|
Conceptual Considerations in Molecular Science Donald T. Sawyer The undergraduate curriculum and associated textbooks include several significant misconceptions. Sawyer, Donald T. J. Chem. Educ. 2005, 82, 985.
Catalysis |
Covalent Bonding |
Electrolytic / Galvanic Cells / Potentials |
Oxidation / Reduction |
Reactions |
Reactive Intermediates |
Thermodynamics |
Water / Water Chemistry
|
Electronegativity and the Bond Triangle Terry L. Meek and Leah D. Garner The dependence of bond type on two parameters, electronegativity difference (??) and average electronegativity (?av), is examined. It is demonstrated that ionic character is governed by the partial charges of the bonded atoms, and metallic character by the HOMOLUMO band gap. Meek, Terry L.; Garner, Leah D. J. Chem. Educ. 2005, 82, 325.
Atomic Properties / Structure |
Covalent Bonding |
Metallic Bonding |
Ionic Bonding |
Main-Group Elements
|
The Molecular Model Game Stephanie A. Myers Student teams must draw Lewis structures and build models of various molecules and polyatomic ions; different team members have different responsibilities. Myers, Stephanie A. J. Chem. Educ. 2003, 80, 423.
Molecular Properties / Structure |
Covalent Bonding |
Lewis Structures |
VSEPR Theory |
Enrichment / Review Materials
|
Understanding and Interpreting Molecular Electron Density Distributions C. F. Matta and R. J. Gillespie A simple introduction to the electron densities of molecules and how they can be analyzed to obtain information on bonding and geometry. Matta, C. F.; Gillespie, R. J. J. Chem. Educ. 2002, 79, 1141.
Covalent Bonding |
Molecular Properties / Structure |
Quantum Chemistry |
Theoretical Chemistry |
Atomic Properties / Structure |
Molecular Modeling |
VSEPR Theory
|
How We Teach Molecular Structure to Freshmen Michael O. Hurst Examination of how textbooks discuss various aspects of molecular structure; conclusion that much of general chemistry is taught the way it is for historical and not pedagogical reasons. Hurst, Michael O. J. Chem. Educ. 2002, 79, 763.
Covalent Bonding |
Atomic Properties / Structure |
Molecular Properties / Structure |
Lewis Structures |
VSEPR Theory |
Valence Bond Theory |
MO Theory
|
The Role of Lewis Structures in Teaching Covalent Bonding S. R. Logan Difficulties with the Lewis theory of covalent bonding and upgrading it to the Molecular Orbital theory. Logan, S. R. J. Chem. Educ. 2001, 78, 1457.
Covalent Bonding |
MO Theory |
Nonmajor Courses |
Learning Theories |
Lewis Structures |
Molecular Properties / Structure
|
An Investigation of the Value of Using Concept Maps in General Chemistry Gayle Nicoll, Joseph S. Francisco, and Mary B. Nakhleh Study of the degree to which students in introductory chemistry classes linked related concepts; comparisons of a class in which concept mapping was used and another in which it was not. Nicoll, Gayle; Francisco, Joseph S.; Nakhleh, Mary B. J. Chem. Educ. 2001, 78, 1111.
Covalent Bonding |
Learning Theories
|
Electronegativity and Bond Type: Predicting Bond Type Gordon Sproul Important limitations with using electronegativity differences to determine bond type and recommendations for using electronegativities in general chemistry. Sproul, Gordon. J. Chem. Educ. 2001, 78, 387.
Covalent Bonding |
Materials Science |
Periodicity / Periodic Table |
Ionic Bonding |
Atomic Properties / Structure |
Metallic Bonding
|
The Use of Molecular Modeling and VSEPR Theory in the Undergraduate Curriculum to Predict the Three-Dimensional Structure of Molecules Brian W. Pfennig and Richard L. Frock Despite the simplicity and elegance of the VSEPR model, however, students often have difficulty visualizing the three-dimensional shapes of molecules and learning the more subtle features of the model, such as the bond length and bond angle deviations from ideal geometry that accompany the presence of lone pair or multiple bond domains or that result from differences in the electronegativity of the bonded atoms, partial charges and molecular dipole moments, and site preferences in the trigonal bipyramidal electron geometry. Pfennig, Brian W.; Frock, Richard L. J. Chem. Educ. 1999, 76, 1018.
Molecular Modeling |
Molecular Properties / Structure |
Covalent Bonding |
VSEPR Theory
|
Lewis Structures Are Models for Predicting Molecular Structure, Not Electronic Structure Gordon H. Purser This article argues against a close relationship between Lewis dot structures and electron structure obtained from quantum mechanical calculations. Lewis structures are a powerful tool for structure prediction, though they are classical models of bonding and do not predict electronic structure. Purser, Gordon H. J. Chem. Educ. 1999, 76, 1013.
Molecular Properties / Structure |
Covalent Bonding |
Computational Chemistry |
Quantum Chemistry |
MO Theory |
Learning Theories |
Lewis Structures |
Molecular Modeling
|
An Alternative Framework for Chemical Bonding William R. Robinson Recent, qualitative research in science education has uncovered many nave or incorrect ideas about aspects of science commonly held by students and others at all levels. This article discusses how misconceptions can cluster and compound. Robinson, William R. J. Chem. Educ. 1998, 75, 1074.
Covalent Bonding |
Ionic Bonding
|
Teaching Chemistry with Electron Density Models Gwendolyn P. Shusterman and Alan J. Shusterman This article describes a powerful new method for teaching students about electronic structure and its relevance to chemical phenomena. This method, developed and used for several years in general chemistry and organic chemistry courses, relies on computer-generated three-dimensional models of electron density distributions. Shusterman, Gwendolyn P.; Shusterman, Alan J. J. Chem. Educ. 1997, 74, 771.
Learning Theories |
Computational Chemistry |
Molecular Modeling |
Quantum Chemistry |
Atomic Properties / Structure |
Covalent Bonding |
Ionic Bonding |
Noncovalent Interactions
|
A Quantitative van Arkel Diagram Jensen, William B. Using van Arkel diagrams to schematically represent relationships between ionic, covalent, and metallic bonds. Jensen, William B. J. Chem. Educ. 1995, 72, 395.
Covalent Bonding |
Ionic Bonding |
Metallic Bonding
|
Classifying Substances by Electrical Character: An Alternative to Classifying by Bond Type Nelson, P. G. An alternative classification of substances based on their electrical properties. Nelson, P. G. J. Chem. Educ. 1994, 71, 24.
Conductivity |
Covalent Bonding |
Ionic Bonding |
Metallic Bonding |
Semiconductors
|
Electronegativity and bond type: I. Tripartate separation Sproul, Gordon D. As a unifying concept of bonding, electronegativity has been widely applied but gets only a limited treatment in most general chemistry texts. Sproul, Gordon D. J. Chem. Educ. 1993, 70, 531.
Ionic Bonding |
Covalent Bonding |
Electrochemistry
|
Magnetic marbles as teaching aids Hill, John W. Magnetic marbles are valuable teaching aids for teachers who have steel chalkboards in their classroom. Hill, John W. J. Chem. Educ. 1990, 67, 320.
Atomic Properties / Structure |
Covalent Bonding |
Ion Exchange
|
The chemical bond DeKock, Roger L. Overview of the chemical bond; considers ionic bonds, covalent bonds, Lewis electron dot structures, polar molecules and hydrogen bonds, and bonding in solid-state elements. DeKock, Roger L. J. Chem. Educ. 1987, 64, 934.
Ionic Bonding |
Covalent Bonding |
Hydrogen Bonding |
Solid State Chemistry |
Lewis Structures |
Molecular Properties / Structure
|
No rabbit ears on water. The structure of the water molecule: What should we tell the students? Laing, Michael Analysis of the bonding found in water and how it results in the observed geometry of the water molecule. Laing, Michael J. Chem. Educ. 1987, 64, 124.
Molecular Properties / Structure |
MO Theory |
Covalent Bonding
|
Is the theoretical emperor really wearing any clothes? Sanderson, R. T. The author asserts that general chemistry material both pushes material of doubtful value and omits material that is useful to many. Sanderson, R. T. J. Chem. Educ. 1986, 63, 845.
Theoretical Chemistry |
Quantum Chemistry |
Atomic Properties / Structure |
Covalent Bonding |
Ionic Bonding |
Noncovalent Interactions
|
Coulombic models in chemical bonding. II. Dipole moments of binary hydrides Sacks, Lawrence J. A discussion of Coulumbic models and their aid in understanding chemical bonding. Sacks, Lawrence J. J. Chem. Educ. 1986, 63, 373.
Electrochemistry |
Molecular Properties / Structure |
Covalent Bonding |
Noncovalent Interactions
|
Competition analogy Felty, Wayne L. Using football competition as an analogy for bond polarity. Felty, Wayne L. J. Chem. Educ. 1985, 62, 869.
Covalent Bonding |
Atomic Properties / Structure
|
Polar Covalence (Sanderson, R. T.) Sturgeon, George D.
Sturgeon, George D. J. Chem. Educ. 1984, 61, A327.
Covalent Bonding
|
Models to depict hybridization of atomic orbitals Stubblefield, C. T. Six models of hybridization: linear, trigonal, tetrahedral, planar, trigonal bipyrimidal, and octahedral. Stubblefield, C. T. J. Chem. Educ. 1984, 61, 158.
Atomic Properties / Structure |
Molecular Modeling |
Covalent Bonding |
Coordination Compounds
|
A needed replacement for the customary description of chemical bonding Sanderson, R. T. Description of and encouragement to use an alternative to the covalent / ionic model for chemical bonding. Sanderson, R. T. J. Chem. Educ. 1982, 59, 376.
Covalent Bonding |
Ionic Bonding
|
The Nature of the Chemical Bond, Review 1 (Pauling, Linus) Roe, Robert, Jr. Classic book on the valence-bond theory of chemical bonding. Roe, Robert, Jr. J. Chem. Educ. 1982, 59, 260.
Covalent Bonding
|
Prospects and retrospects in chemical education Pauling, Linus Pauling provides suggestions for what concepts to focus on in an elementary chemistry course. Pauling, Linus J. Chem. Educ. 1980, 57, 38.
Covalent Bonding |
Descriptive Chemistry |
Molecular Properties / Structure
|
Physical and chemical properties and bonding of metallic elements Myers, R. Thomas 137. Common textbook errors concerning the physical and chemical properties, conductivity and bonding of metals. Myers, R. Thomas J. Chem. Educ. 1979, 56, 712.
Physical Properties |
Metallic Bonding |
Metals |
Covalent Bonding
|
Electronegativity, bond energy, and chemical reactivity Myers, R. Thomas The Pauling electronegativity concept can be used to help rationalize several kinds of chemical reactions. Myers, R. Thomas J. Chem. Educ. 1979, 56, 711.
Atomic Properties / Structure |
Covalent Bonding |
Reactions
|
Loosely-bound diatomic molecules Balfour, W. J. Over the past decade, careful spectroscopic studies have established the existence of bound rare gas and alkaline earth diatomic molecules. Balfour, W. J. J. Chem. Educ. 1979, 56, 452.
Covalent Bonding |
Molecular Properties / Structure
|
Lecture projectable atomic orbital cross-sections and bonding interactions Shepherd, Rex E. Models using small Styrofoam balls and slinky toys improve student understanding of covalent bonds. Shepherd, Rex E. J. Chem. Educ. 1978, 55, 317.
Atomic Properties / Structure |
Covalent Bonding |
MO Theory |
Molecular Modeling
|
Chemical aspects of Bohr's 1913 theory Kragh, Helge The chemical content of Bohr's 1913 theory has generally been neglected in the treatises on the history of chemistry; this paper regards Bohr as a theoretical chemist and discusses the chemical aspects of his atomic theory. Kragh, Helge J. Chem. Educ. 1977, 54, 208.
Periodicity / Periodic Table |
Atomic Properties / Structure |
Molecular Properties / Structure |
Covalent Bonding |
Theoretical Chemistry
|
Strength of chemical bonds Christian, Jerry D. Demonstrating the strength of chemical bonds by scaling a molecule up to a macroscopic size. Christian, Jerry D. J. Chem. Educ. 1973, 50, 176.
Covalent Bonding |
Molecular Properties / Structure |
Metallic Bonding
|
Solubility and the chemistry of the covalent bond: More on DDT - A substituted alkyl halide Hill, John W. Discusses applications of the insolubility of DDT in water and its solubility in covalent fatty tissues. Hill, John W. J. Chem. Educ. 1970, 47, 634.
Covalent Bonding |
Precipitation / Solubility |
Agricultural Chemistry |
Applications of Chemistry |
Molecular Properties / Structure
|
The electron-pair repulsion model for molecular geometry Gmespie, R. J. Reviews the electron-pair repulsion model for molecular geometry and examines three-centered bonds, cluster compounds, bonding among the transition elements, and exceptions to VSEPR rules. Gmespie, R. J. J. Chem. Educ. 1970, 47, 18.
Molecular Properties / Structure |
Covalent Bonding |
MO Theory |
VSEPR Theory |
Transition Elements
|
Ionic versus covalent bonding Goldish, Dorothy M. Ionic sodium chloride dissolves in water but covalent benzyl chloride does not. Goldish, Dorothy M. J. Chem. Educ. 1969, 46, A497.
Ionic Bonding |
Covalent Bonding |
Aqueous Solution Chemistry |
Precipitation / Solubility
|
Molecular geometry: Bonded versus nonbonded interactions Bartell, L. S. Proposes simplified computational models to facilitate a comparison between the relative roles of bonded and nonbonded interactions in directed valence. Bartell, L. S. J. Chem. Educ. 1968, 45, 754.
Molecular Properties / Structure |
VSEPR Theory |
Molecular Modeling |
Covalent Bonding |
Noncovalent Interactions |
Valence Bond Theory |
MO Theory
|
Why does methane burn? Sanderson, R. T. A thermodynamic explanation for why methane burns. Sanderson, R. T. J. Chem. Educ. 1968, 45, 423.
Thermodynamics |
Reactions |
Oxidation / Reduction |
Calorimetry / Thermochemistry |
Covalent Bonding |
Ionic Bonding
|
Bond energies in the interpretation of descriptive chemistry Howald, Reed A. Most of the discrepancy between bond energies and bond dissociation energies is eliminated by the inclusion of pi bonding effects and using bond energies referred to as hypothetical "valence state" atoms in those cases where spin pairing provides substantial stabilization for the free atom. Howald, Reed A. J. Chem. Educ. 1968, 45, 163.
Descriptive Chemistry |
Covalent Bonding
|
Atomic structure. Radioactivity (continued) Alyea, Hubert N. Formation of the complex Cu(NH3)4++ as an example of coordinate covalent bonding and hydrogen bonding as evidenced by viscosity. Alyea, Hubert N. J. Chem. Educ. 1967, 44, A599.
Coordination Compounds |
Covalent Bonding |
Hydrogen Bonding |
Liquids
|
The electron repulsion theory of the chemical bond. I. New models of atomic structure Luder, W. F. Describes the electron repulsion theory of electron configuration and applies it to representative elements. Luder, W. F. J. Chem. Educ. 1967, 44, 206.
Atomic Properties / Structure |
Covalent Bonding |
Metals
|
Models illustrating d orbitals involved in multiple bonding Barrett, Edward J. Describes the use of Framework Molecular Orbital Models to illustrate the d orbitals involved in multiple bonding Barrett, Edward J. J. Chem. Educ. 1967, 44, 146.
Atomic Properties / Structure |
Molecular Modeling |
Covalent Bonding
|
IV - Isoelectronic systems Bent, Henry A. A detailed consideration of the principles of isoelectric systems. Bent, Henry A. J. Chem. Educ. 1966, 43, 170.
Gases |
Nonmetals |
Covalent Bonding
|
III - Bond energies Benson, Sidney W. Examines bond dissociation energies , methods for measuring such energies, some representative values of such energies, structural aspects of bond dissociation energies, and bond energies in ionized species. Benson, Sidney W. J. Chem. Educ. 1965, 42, 502.
Covalent Bonding
|
Experiments on metal amine salts Haight, G. P., Jr. Tetrammine monaquo copper(II) sulfate is prepared and studied qualitatively and quantitatively. Haight, G. P., Jr. J. Chem. Educ. 1965, 42, 468.
Metals |
Covalent Bonding |
Hydrogen Bonding |
Qualitative Analysis |
Quantitative Analysis
|
Tangent-sphere models of molecules. III. Chemical implications of inner-shell electrons Bent, Henry A. While a study of atomic core sizes might seem to hold little promise of offering interesting insights into the main body of chemical theory, it is demonstrated here that from such a study emerges a picture of chemical bonding that encompasses as particular cases covalent, ionic, and metallic bonds. Bent, Henry A. J. Chem. Educ. 1965, 42, 302.
Atomic Properties / Structure |
Molecular Properties / Structure |
Molecular Modeling |
Covalent Bonding |
Ionic Bonding |
Metallic Bonding
|
An atomic and molecular orbital models kit Stone, A. Harris; Siegelman, Irwin The models presented here allows one to see the overlap that constitutes covalent bonds. Stone, A. Harris; Siegelman, Irwin J. Chem. Educ. 1964, 41, 395.
Atomic Properties / Structure |
Molecular Modeling |
Molecular Properties / Structure |
Covalent Bonding
|
The chemistry of the noble gases Hyman, Herbert H. Summarizes the chemistry of the noble gases and their bond-forming abilities. Hyman, Herbert H. J. Chem. Educ. 1964, 41, 174.
Gases |
Main-Group Elements |
Covalent Bonding
|
Principles of chemical reaction Sanderson, R. T. The purpose of this paper is to examine the nature of chemical change in the hope of recognizing and setting forth the basic principles that help us to understand why they occur. Sanderson, R. T. J. Chem. Educ. 1964, 41, 13.
Reactions |
Thermodynamics |
Mechanisms of Reactions |
Kinetics |
Synthesis |
Covalent Bonding |
Ionic Bonding |
Metallic Bonding
|
A classical electrostatic view of chemical forces Jaffe, H. H. This paper reviews the different types of forces involved in the formation of chemical compounds, solids and liquids. Jaffe, H. H. J. Chem. Educ. 1963, 40, 649.
Covalent Bonding |
Ionic Bonding |
Metallic Bonding |
Noncovalent Interactions
|
Tangent-sphere models of molecules. II. Uses in Teaching Bent, Henry A. Tangent-sphere models can be used to represent highly strained bonds and multicentered bonds, atoms with expanded and contracted octets, inter- and intramolecular interactions, and the effects of electronegative groups, lone pairs, and multiple bonds on molecular geometry, bond properties, and chemical reactivity. Bent, Henry A. J. Chem. Educ. 1963, 40, 523.
Molecular Properties / Structure |
Covalent Bonding
|
Chemical bonding and the geometry of molecules (Ryschkewitsch, George E.) Eblin, Lawrence P.
Eblin, Lawrence P. J. Chem. Educ. 1963, 40, 441.
Molecular Properties / Structure |
Covalent Bonding
|
The valence-shell electron-pair repulsion (VSEPR) theory of directed valency Gillespie, R. J. Presents the valence-shell electron-pair repulsion (VSEPR) theory of directed valency and its use to determine molecular shapes, bond angles, and bond lengths. Gillespie, R. J. J. Chem. Educ. 1963, 40, 295.
VSEPR Theory |
Molecular Properties / Structure |
Covalent Bonding
|
Non-existent compounds Dasent, W. E. The purpose of this review is to examine compounds that do not violate the rules of valence but which are nevertheless characterized by a high degree of instability, and to consider why these structures are unstable or non-existent. Dasent, W. E. J. Chem. Educ. 1963, 40, 130.
Molecular Properties / Structure |
Covalent Bonding
|
Acids, Bases, and the Chemistry of the Covalent Bond (VanderWerf, Calvin A.) Eblin, Lawrence P.
Eblin, Lawrence P. J. Chem. Educ. 1962, 39, 273.
Acids / Bases |
Covalent Bonding
|
Demonstrations of simple bonding using magnets Baker, Wilbur L. Demonstrates a variety of bonding using iron washers, magnets, and steel balls. Baker, Wilbur L. J. Chem. Educ. 1962, 39, 131.
Covalent Bonding |
Ionic Bonding |
Metallic Bonding
|
Principles of chemical bonding Sanderson, R. T. Develops, through 25 statements, the basic principles of chemical bonding. Sanderson, R. T. J. Chem. Educ. 1961, 38, 382.
Covalent Bonding |
Metallic Bonding |
Ionic Bonding |
Atomic Properties / Structure |
Molecular Properties / Structure
|
Dynamic projector display for atomic orbitals and the covalent bond Thompson, H. Bradford An overhead projector is used to display the combination of simple atomic orbitals to form hybrid and molecular orbitals. Thompson, H. Bradford J. Chem. Educ. 1960, 37, 118.
Atomic Properties / Structure |
Covalent Bonding
|
Molecular models: A general chemistry exercise Pierce, James B. Students are provided a list of bond angles, covalent radii, and van der Waals radii, and sufficient polystyrene spheres, and then asked to construct models of molecules and ions. Pierce, James B. J. Chem. Educ. 1959, 36, 595.
Molecular Modeling |
Molecular Properties / Structure |
Covalent Bonding
|
Some aspects of organic molecules and their behavior. II. Bond energies Reinmuth, Otto Examines bond and dissociation energies, the "constancy" of C-H and C-C dissociation energies, and some common types of organochemical reactions. Reinmuth, Otto J. Chem. Educ. 1957, 34, 318.
Covalent Bonding |
Molecular Properties / Structure |
Reactions
|
Some aspects of organic molecules and their behavior. II. Bond energies Reinmuth, Otto Examines bond and dissociation energies, the "constancy" of C-H and C-C dissociation energies, and some common types of organochemical reactions. Reinmuth, Otto J. Chem. Educ. 1957, 34, 318.
Covalent Bonding |
Molecular Properties / Structure |
Reactions
|
A chart of chemical compounds based on electronegativities Yeh, Ping-Yuan This short note presents a chart of chemical compounds based on the relative electronegativities of the elements. Yeh, Ping-Yuan J. Chem. Educ. 1956, 33, 134.
Covalent Bonding |
Metallic Bonding |
Ionic Bonding
|
Note on the representation of the electronic structures of acetylene and benzene Noller, Carl R. The three dimensional nature of molecular orbitals in acetylene and benzene are illustrated. Noller, Carl R. J. Chem. Educ. 1955, 32, 23.
Alkenes |
Alkynes |
Aromatic Compounds |
Molecular Properties / Structure |
Covalent Bonding |
MO Theory
|
An unconventional representation of multiple bonds Gillis, Richard G.; Nelson, Peter F. There are several advantages to differentiating between sigma and pi electrons in representing multiple bonds. Gillis, Richard G.; Nelson, Peter F. J. Chem. Educ. 1954, 31, 546.
Covalent Bonding
|
Electronegativities in inorganic chemistry. III Sanderson, R. T. The purpose of this paper is to illustrate some of the practical applications of electronegativities and charge distribution. Sanderson, R. T. J. Chem. Educ. 1954, 31, 238.
Atomic Properties / Structure |
Covalent Bonding |
Acids / Bases
|
Chemistry of the covalent bond: The first-year course at Brown Clapp, Leallyn B. Provides an outline of the first-year chemistry course at Brown University, "The Chemistry of the Covalent Bond." Clapp, Leallyn B. J. Chem. Educ. 1953, 30, 530.
Covalent Bonding
|
|