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Quantitative Acid-Base Titration An acid-base titration is demonstrated along with variations in technique for handling stopcocks.
Quantitative Analysis |
Titration / Volumetric Analysis |
Acids / Bases
Conductimetric Titration Aqueous sulfuric acid and barium hydroxide both conduct electricity; distilled water does not. As barium hydroxide solution is added to sulfuric acid, conductivity decreases until it reaches zero at the equivalence point. As excess barium hydroxide is added, the conductivity gradually increases.
Acids / Bases |
Conductivity |
Titration / Volumetric Analysis
A Complete Acid-Base Titration A solid acid is dissolved in deionized water and titrated with sodium hydroxide solution using the color change of an indictor to determine the endpoint.
Flame Emission Spectrometry in General Chemistry Labs: Solubility Product (Ksp) of Potassium Hydrogen PhthalateFrazier W. Nyasulu, William Cusworth III, David Lindquist, and John Mackin In this general chemistry laboratory, flame emission spectrometry is used to determine the potassium ion concentration in saturated solutions of potassium hydrogen phthalate. From these data the solubility products, the Gibbs free energies of solution, the standard enthalpy of solution, and the standard entropy of solution are calculated. Nyasulu, Frazier W.; Cusworth, William, III; Lindquist, David; Mackin, John. J. Chem. Educ.2007, 84, 456.
Acids / Bases |
Atomic Properties / Structure |
Spectroscopy |
Equilibrium |
Quantitative Analysis |
Thermodynamics |
Titration / Volumetric Analysis |
Solutions / Solvents |
Aqueous Solution Chemistry |
Atomic Spectroscopy
Titration of a Solid Acid Monitored By X-Ray DiffractionKeenan E. Dungey and Paul Epstein Presents a solid-state laboratory in which students react fixed amounts of zirconium phosphate with increasing equivalents of NaOH(aq). From X-ray diffraction patterns, students calculate the interplanar spacings before and after the reaction. The spacings increase until the molar equivalence point is reached, indicating incorporation of the sodium ion into the crystal. Dungey, Keenan E.; Epstein, Paul. J. Chem. Educ.2007, 84, 122.
ChemPaths 104 F Apr 15John W. Moore Today in Chem 104:
* Lecture: Titration; Lewis Acids and Bases
* Reading:
Kotz: Ch. 18, Sec. 3; Ch. 17, Sec. 9
Moore: Ch. 17, Sec. 2; Ch. 16, Sec.
* Homework #10 due by 11:55 PM tonight
Lewis Acids / Bases |
Titration / Volumetric Analysis
Introduction of Aquatic Chemistry in General Chemistry Curriculum;Spreadsheet Calculation ApproachesChulsung Kim Fundamental aquatic chemistry concepts may be introduced in general chemistry classes by computing ionization fractions and buffer intensity of aqueous phase carbonate systems. This Excel spreadsheet may used to build graphic presentations of a titration curve, distribution diagram, and buffer intensity as a function of pH. Accompanying activities are designed to enhance the concepts of acid-base equilibrium through exploring the relationship between pKa/pKb, pH of the solution, ionization fractions, and buffer intensity, and to exercise students graphing skills.
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Titration / Volumetric Analysis |
Water / Water Chemistry |
Equilibrium
Principal Species and pHRobert M. Hanson Calculates concentrations of principal species in solutions using JavaScript. You can specify whether "1st-year" methods or mass-charge balance methods are used in the calculations. Solutions can be chosen from the included set or you can design your own.
