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Discovery VideosLyubov Hoffman Laroche, Gary Wulfsberg, Barbara Young The use of digital video for instruction has many advantages. In many situations the only way to present some chemical phenomena is through the use of video. The two video lessons presented here are examples intended to supplement our article in the August 2003 issue of JCE.
Descriptive Chemistry |
Periodicity / Periodic Table
Paramagnetism: Compounds Vials of a number of compounds (NaCl, MnSO4, FeSO4, CoCl2, NiSO4, ZnSO4, K4Fe(CN)6, [Co(NH3)6]Cl3, [Ni(NH3)6]Cl2, and H2O) are hung from a thread. When a magnet is brought near, some of the vials are attracted.
Magnetic Properties |
Atomic Properties / Structure
Paramagnetism: Oxidation States of Manganese Manganese(III) oxide, with 4 unpaired electrons per Mn atom, is more strongly attracted to a magnet than is manganese(IV) oxide, with only 3 unpaired electrons per Mn atom. Potassium permanganate, a compound of Mn(VII), has no unpaired electrons and is not attracted to a magnet.
The Correlation of Binary Acid Strengths with Molecular Properties in First-Year ChemistryTravis D. Fridgen This article replaces contradictory explanations for the strengths of different binary acids in first-year chemistry textbooks with a single explanation that uses a BornHaber cycle involving homolyic bond dissociation energies, electron affinities, and ion solvation enthalpies to rationalize trends in the strengths of all binary acids. Fridgen, Travis D. J. Chem. Educ.2008, 85, 1220.
Acids / Bases |
Atomic Properties / Structure |
Aqueous Solution Chemistry |
Physical Properties |
Thermodynamics
Forecasting Periodic Trends: A Semester-Long Team Exercise for Nonscience MajorsJohn Tierney Teams of students in a course for nonscience majors identify trends among the properties of elements in the periodic table, use Excel to plot and produce best-fit equations to describe relationships among those properties, and apply the resulting formulas to predict and justify the properties of missing elements. Tierney, John. J. Chem. Educ.2008, 85, 1215.
Atomic Properties / Structure |
Computational Chemistry |
Main-Group Elements |
Nonmetals |
Periodicity / Periodic Table |
Metals |
Student-Centered Learning
Factors That Influence Relative Acid Strength in Water: A Simple ModelMichael J. Moran The pKa's of diverse aqueous acids HA correlate well with the sum of two gas-phase properties: the HA bond-dissociation enthalpy and the electron affinity of the A radical. It is suggested that rather than bond strength alone or bond polarity, the sum of the enthalpies of these two steps is a fairly good indicator of relative acidity. Moran, Michael J. J. Chem. Educ.2006, 83, 800.