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Solutions Reactions and demonstrations exploring the concepts of solutions.
Noncovalent Interactions |
Physical Properties |
Precipitation / Solubility |
Solutions / Solvents |
Calorimetry / Thermochemistry |
Applications of Chemistry |
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Conductivity |
Reactions |
Titration / Volumetric Analysis |
Liquids |
Solids |
Equilibrium |
Transport Properties
A Complete Acid-Base Titration A solid acid is dissolved in deionized water and titrated with sodium hydroxide solution using the color change of an indictor to determine the endpoint.
Quantitative Analysis |
Titration / Volumetric Analysis |
Acids / Bases
Conductimetric Titration Aqueous sulfuric acid and barium hydroxide both conduct electricity; distilled water does not. As barium hydroxide solution is added to sulfuric acid, conductivity decreases until it reaches zero at the equivalence point. As excess barium hydroxide is added, the conductivity gradually increases.
Reactions : AcidBaseRxns (20 Variations) In order to answer the following questions, write the net ionic equation for the reaction between equal volumes of 0.10 M solutions of the following acid and base:
KOH(aq) + HBr(aq)
What are the reaction products? Does the reaction yield an acidic, basic, or neutral aqueous solution?
A 25.0 mL aliquot of a 1.44M solution of ammonia (Kb = 1.8 x 10-5) is titrated with 1.50M HCl. Use the Indicator Table below to decide which of the indicators listed would most accurately signal the equivalence point for this titration.
Write the letter corresponding to your choice of indicator in the box.
Microscale pH Titrations Using an Automatic PipetEdward B. Flint, Carrie L. Kortz, and Max A. Taylor A technique for microscale pH titrations using 1-5 mL of analyte and titrant. Flint, Edward B.; Kortz, Carrie L.; Taylor, Max A. J. Chem. Educ.2002, 79, 705.
Acids / Bases |
Instrumental Methods |
Microscale Lab |
pH |
Titration / Volumetric Analysis
A Comparative Study of Microscale and Standard BuretsMono M. Singh, Cynthia B. McGowan, Zvi Szafran, and R. M. Pike This paper describes a comparative study of the performance of microscale titrations using 2-mL microscale burets with those using Beral pipets and normal 50- and 10-mL burets. The usefulness of a microburet in general and analytical chemistry is demonstrated by presenting results from acid-base, oxidation-reduction, precipitation, complexometric, and pH titrations. Singh, Mono M.; McGowan, Cynthia B.; Szafran, Zvi; Pike, Ronald M. J. Chem. Educ.2000, 77, 625.
Acids / Bases |
Aqueous Solution Chemistry |
Laboratory Equipment / Apparatus |
Microscale Lab |
Quantitative Analysis |
Oxidation / Reduction |
Titration / Volumetric Analysis |
pH |
Precipitation / Solubility
A Simpler Approach to "Apparent" pKa'sKildahl, Nicholas Addition to a recent article on pH, indicating an approach which emphasizes the chemistry behind the titration of a weak acid. Kildahl, Nicholas J. Chem. Educ.1996, 73, 598.
Principal Species and pHRobert M. Hanson Calculates concentrations of principal species in solutions using JavaScript. You can specify whether "1st-year" methods or mass-charge balance methods are used in the calculations. Solutions can be chosen from the included set or you can design your own.
Acids / Bases |
Titration / Volumetric Analysis |
pH |
Solutions / Solvents
Connected ChemistryMike Stieff Connected Chemistry, a novel learning environment for teaching chemistry, is appropriate for use in both high school and undergraduate chemistry classrooms. Connected Chemistry comprises several molecular simulations designed to enable instructors to teach chemistry using the perspective of emergent phenomena. That is, it allows students to see observed macro-level chemical phenomena, like many other scientific phenomena, as resultant from the interactions of many individual agents on a micro-level. This perspective is especially appropriate to the study of chemistry where the interactions between multitudes of molecules on the atomic level give rise to the macro-level concepts that students study in the classroom. Connected Chemistry comprises molecular simulations embedded in the NetLogo modeling software (1). The collection contains several predesigned simulations of closed chemical systems to teach specific chemistry concepts. Currently, Connected Chemistry contains models for teaching Brønsted Lowry acid base theory, enzyme kinetics, radical polymerization, buffer chemistry, kinetics, chemical equilibrium, and crystallization. Instructors and students can individually tailor the predesigned simulations or generate new simulations as they are needed in the context of a particular lesson, classroom, or department.
Acids / Bases |
Gases |
Kinetics |
Nuclear / Radiochemistry |
pH |
Titration / Volumetric Analysis |
Polymerization |
Equilibrium |
Catalysis
Introduction of Aquatic Chemistry in General Chemistry Curriculum;Spreadsheet Calculation ApproachesChulsung Kim Fundamental aquatic chemistry concepts may be introduced in general chemistry classes by computing ionization fractions and buffer intensity of aqueous phase carbonate systems. This Excel spreadsheet may used to build graphic presentations of a titration curve, distribution diagram, and buffer intensity as a function of pH. Accompanying activities are designed to enhance the concepts of acid-base equilibrium through exploring the relationship between pKa/pKb, pH of the solution, ionization fractions, and buffer intensity, and to exercise students graphing skills.
