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Magnetized Water: Science or Fraud? L. Lahuerta Zamora, G. M. Antón-Fos, P. A. Alemán López, and R. V. Martin Algarra Commercial water magnetizers provide a unique opportunity to help university and secondary students develop appropriate skepticism against extraordinary claims and use testing as the basis for their scientific evaluation. Lahuerta Zamora, L.; Antón-Fos, G. M.; Alemán López, P. A.; Martin Algarra, R. V. J. Chem. Educ. 2008, 85, 1416.
Aqueous Solution Chemistry |
Magnetic Properties |
pH |
Titration / Volumetric Analysis |
Water / Water Chemistry
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Fog Machines, Vapors, and Phase Diagrams Ed Vitz This series of demonstrations elucidate the operation of commercial fog machines using common laboratory materials and can be adapted for elementary through tertiary levels. The formation of fogs is discussed in terms of the phase diagram for water and other chemical principles. Vitz, Ed. J. Chem. Educ. 2008, 85, 1385.
Liquids |
Phases / Phase Transitions / Diagrams |
Physical Properties |
Water / Water Chemistry
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Greener Alternative to Qualitative Analysis for Cations without H2S and Other Sulfur-Containing Compounds Indu Tucker Sidhwani and Sushmita Chowdhury The classic technique for the qualitative analysis of inorganic salts and mixtures relies on highly toxic hydrogen sulfide. Increasing environmental awareness has prompted the development of a green scheme for the detection of cations by spot tests that is simple and fast. Sidhwani, Indu Tucker; Chowdhury, Sushmita. J. Chem. Educ. 2008, 85, 1099.
Green Chemistry |
Qualitative Analysis |
Separation Science
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Stilling Waves with Ordered Molecular Monolayers Ed Vitz The amazing ability of a film of oil one molecule thick to dissipate the relatively large energy of water waves can be readily demonstrated, but an explanation of the effect has been elusive until recently. Vitz, Ed. J. Chem. Educ. 2008, 85, 1064.
Lipids |
Molecular Properties / Structure |
Noncovalent Interactions |
Surface Science |
Water / Water Chemistry |
Fatty Acids
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Developing and Disseminating NOP: An Online, Open-Access, Organic Chemistry Teaching Resource To Integrate Sustainability Concepts in the Laboratory Johannes Ranke, Müfit Bahadir, Marco Eissen, and Burkhard König Describes a project that identifies parameters for sustainable practices in organic chemistry laboratories, including the atom economy and energy efficiency of chemical transformations, questions of waste and renewable feedstocks, toxicity and ecotoxicity, and safety measures. Ranke, Johannes; Bahadir, Müfit; Eissen, Marco; König, Burkhard. J. Chem. Educ. 2008, 85, 1000.
Green Chemistry |
Synthesis |
Toxicology
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Determination of the Formula of a Hydrate: A Greener Alternative Marc A. Klingshirn, Allison F. Wyatt, Robert M. Hanson, and Gary O. Spessard This article describes how the principles of green chemistry were applied to a first-semester, general chemistry courses, specifically in relation to the determination of the formula of a copper hydrate salt that changes color when dehydrated and is easily rehydrated with steam. Klingshirn, Marc A.; Wyatt, Allison F.; Hanson, Robert M.; Spessard, Gary O. J. Chem. Educ. 2008, 85, 819.
Gravimetric Analysis |
Green Chemistry |
Solids |
Stoichiometry
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Yet Another Variation on the Electrolysis of Water at Iron Nails Mark T. Stauffer and Justin P. Fox Describes a variation on the electrolysis of water with iron nails in which a sharp contrast in the colors produced effectively demonstrates electrolysis and the diffusion of oxidized and reduced species from the electrodes. Stauffer, Mark T.; Fox, Justin P. J. Chem. Educ. 2008, 85, 523.
Acids / Bases |
Electrochemistry |
Oxidation / Reduction |
Stoichiometry |
Water / Water Chemistry |
Electrolytic / Galvanic Cells / Potentials
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Understanding the Clausius–Clapeyron Equation by Employing an Easily Adaptable Pressure Cooker Monica Galleano, Alberto Boveris, and Susana Puntarulo Describes a laboratory exercise to understand the effect of pressure on phase equilibrium as described by the ClausiusClapeyron equation. The equipment required is a pressure cooker adapted with a pressure gauge and a thermometer in the lid, allowing the measurement of the pressure and the temperature of the chamber containing the water heated until vaporization. Galleano, Monica; Boveris, Alberto; Puntarulo, Susana. J. Chem. Educ. 2008, 85, 276.
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Water / Water Chemistry
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Connecting Solubility, Equilibrium, and Periodicity in a Green, Inquiry Experiment for the General Chemistry Laboratory Kristen L. Cacciatore, Jose Amado, Jason J. Evans, and Hannah Sevian Presents a novel first-year chemistry experiment that asks students to replicate procedures described in sample lab reports that lack essential information. This structure is designed to promote students' experimental design and data analysis skills as well as their understanding of the importance and essential qualities of written and verbal communication between scientists. Cacciatore, Kristen L.; Amado, Jose; Evans, Jason J.; Sevian, Hannah. J. Chem. Educ. 2008, 85, 251.
Equilibrium |
Green Chemistry |
Periodicity / Periodic Table |
Solutions / Solvents |
Stoichiometry |
Titration / Volumetric Analysis
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The Role of Water Chemistry in Marine Aquarium Design: A Model System for a General Chemistry Class Jeffrey J. Keaffaber, Ramiro Palma, and Kathryn R. Williams Water chemistry is central to aquarium design, and it provides many potential applications for discussion in undergraduate chemistry and engineering courses. This article uses a hypothetical tank to house ocean sunfish as a model to show students the calculations and other considerations that are needed when designing a marine aquarium. Keaffaber, Jeffrey J.; Palma, Ramiro; Williams, Kathryn R. J. Chem. Educ. 2008, 85, 225.
Acids / Bases |
Aqueous Solution Chemistry |
Consumer Chemistry |
Oxidation / Reduction |
Stoichiometry |
Water / Water Chemistry
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A Simplified Model To Predict the Effect of Increasing Atmospheric CO2 on Carbonate Chemistry in the Ocean Brian J. Bozlee, Maria Janebo, and Ginger Jahn The chemistry of dissolved inorganic carbon in seawater is reviewed and used to predict the potential effect of rising levels of carbon dioxide in the atmosphere. It is found that calcium carbonate may become unsaturated in cold surface seawater by the year 2100, resulting in the destruction of calcifying organisms such as coral. Bozlee, Brian J.; Janebo, Maria; Jahn, Ginger. J. Chem. Educ. 2008, 85, 213.
Applications of Chemistry |
Aqueous Solution Chemistry |
Atmospheric Chemistry |
Equilibrium |
Green Chemistry |
Water / Water Chemistry
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JCE Resources for Chemistry and Water Erica K. Jacobsen This annotated bibliography collects the best that past issues of JCE have to offer for use with the 2008 Chemists Celebrate Earth Day theme, "Streaming Chemistry". Jacobsen, Erica K. J. Chem. Educ. 2008, 85, 188.
Water / Water Chemistry
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Streaming Chemistry John W. Moore The JCE editorial staff has collected a broad range of articles in support of the topic Water, this years theme for Chemists Celebrate Earth Day. Moore, John W. J. Chem. Educ. 2008, 85, 171.
Water / Water Chemistry
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Colorful Lather Printing Susan A. S. Hershberger, Matt Nance, Arlyne M. Sarquis, and Lynn M. Hogue Students explore the chemistry of polar and nonpolar substances and surfactants while marbling paper with shaving cream and food coloring. Hershberger, Susan A. S.; Nance, Matt; Sarquis, Arlyne M.; Hogue, Lynn M. J. Chem. Educ. 2007, 84, 608A.
Applications of Chemistry |
Consumer Chemistry |
Noncovalent Interactions |
Physical Properties |
Surface Science |
Water / Water Chemistry
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New Analytical Method for the Determination of Detergent Concentration in Water by Fabric Dyeing Set Seng, Masakazu Kita, and Reiko Sugihara This article describes a high school classroom activity in which an acrylic fabric is used as the extraction medium in the analysis of detergent concentration rather than more harmful organic solvents. An handmade reflection photometer, assembled with inexpensive materials such as LED, PVC tube, and CdS sensor, is used to determine the detergent concentration. Seng, Set; Kita, Masakazu; Sugihara, Reiko. J. Chem. Educ. 2007, 84, 1803.
Aqueous Solution Chemistry |
Consumer Chemistry |
Dyes / Pigments |
Laboratory Equipment / Apparatus |
Quantitative Analysis |
Solutions / Solvents |
Water / Water Chemistry
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Gas Clathrate Hydrates Experiment for High School Projects and Undergraduate Laboratories Melissa P. Prado, Annie Pham, Robert E. Ferazzi, Kimberly Edwards, and Kenneth C. Janda Presents a procedure for preparing and studying propane clathrate hydrate. This experiment introduces students to this unusual solid while stimulating a discussion of the interplay of intermolecular forces, thermodynamics, and solid structure. Prado, Melissa P.; Pham, Annie; Ferazzi, Robert E.; Edwards, Kimberly; Janda, Kenneth C. J. Chem. Educ. 2007, 84, 1790.
Alkanes / Cycloalkanes |
Applications of Chemistry |
Calorimetry / Thermochemistry |
Gases |
Phases / Phase Transitions / Diagrams |
Thermodynamics |
Water / Water Chemistry |
Hydrogen Bonding
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The Chemistry of Swimming Pool Maintenance Carl Salter and David L. Langhus This paper examines the key ideas behind swimming pool chemistry -- the central importance of pH and its effect on chlorine sanitation and calcium carbonate solubility. The paper also reviews the analytical procedures and common practices used to monitor and control pool chemistry or correct problems. Salter, Carl; Langhus, David L. J. Chem. Educ. 2007, 84, 1124.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Dyes / Pigments |
pH |
Photochemistry |
Precipitation / Solubility |
Water / Water Chemistry
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Molecular Model of Zincon William F. Coleman The Featured Molecules this month are the tautomeric forms of the colorimetric reagent zincon. The structures could be used as an introduction to the concept of tautomerism, with students being asked to develop a definition of the term based on their observations of the difference(s) in linkage in the two forms. Coleman, William F. J. Chem. Educ. 2007, 84, 305.
Biological Cells |
Calorimetry / Thermochemistry |
Water / Water Chemistry |
Molecular Mechanics / Dynamics |
Molecular Modeling |
Molecular Properties / Structure
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Popcorn—What's in the Bag? Marissa B. Sherman and Thomas A. Evans Three independent activities explore microwave popcorn, the nature of the packaging, and the popcorn produced. Sherman, Marissa B.; Evans, Thomas A. J. Chem. Educ. 2006, 83, 416A.
Carbohydrates |
Nutrition |
Physical Properties |
Solutions / Solvents |
Water / Water Chemistry
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Equilibrium Constants and Water Activity Revisited David Keeports Subtle arguments based upon the use of chemical potentials show that numerical values of solute molar concentrations can be used as good approximate activities in equilibrium calculations for reactions involving dilute solutions. Keeports, David. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
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Equilibrium Constants and Water Activity Revisited E. J. Behrman In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols. Behrman, E. J. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
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Equilibrium Constants and Water Activity Revisited E. J. Behrman In teaching the effects of structure on acid strength, it is useful to compare, inter alia, water with primary alcohols. Behrman, E. J. J. Chem. Educ. 2006, 83, 1290.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry |
Alcohols
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Completing Our Education. Green Chemistry in the Curriculum Birgit Braun, Reagan Charney, Andres Clarens, Jennifer Farrugia, Christopher Kitchens, Carmen Lisowski, David Naistat, and Adam O'Neil Identifies areas of green chemistry that are often neglected, describes the value of integrating green chemistry principles in today's curricula, and and suggests strategies educators might use to incorporate green chemistry in their classrooms. Braun, Birgit; Charney, Reagan; Clarens, Andres; Farrugia, Jennifer; Kitchens, Christopher; Lisowski, Carmen; Naistat, David; O'Neil, Adam. J. Chem. Educ. 2006, 83, 1126.
Green Chemistry
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Faculty Responsibilities John W. Moore It is important that students recognize the objectives of green chemistry, its ways of analyzing environmental impacts and sustainability, and how those objectives and methods can lead to creativity in solving scientific and technical problems. These can be applied to existing content and merely require a different approach to many things we already teach. Moore, John W. J. Chem. Educ. 2006, 83, 1111.
Administrative Issues |
Professional Development |
Green Chemistry
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Enantioselective Reduction by Crude Plant Parts: Reduction of Benzofuran-2-yl Methyl Ketone with Carrot (Daucus carota) Bits Silvana Ravía, Daniela Gamenara, Valeria Schapiro, Ana Bellomo, Jorge Adum, Gustavo Seoane, and David Gonzalez Presents the enantioselective reduction of a ketone by crude plant parts, using carrot (Daucus carota) as the reducing agent. Ravía, Silvana; Gamenara, Daniela; Schapiro, Valeria; Bellomo, Ana; Adum, Jorge; Seoane, Gustavo; Gonzalez, David. J. Chem. Educ. 2006, 83, 1049.
Aldehydes / Ketones |
Biotechnology |
Catalysis |
Chromatography |
Green Chemistry |
Oxidation / Reduction |
Stereochemistry |
Separation Science
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Teaching Lab Report Writing through Inquiry: A Green Chemistry Stoichiometry Experiment for General Chemistry Kristen L. Cacciatore and Hannah Sevian Presents an experiment with four key features: students utilize stoichiometry, learn and apply principles of green chemistry, engage in authentic scientific inquiry, and discover why each part of a scientific lab report is necessary. Cacciatore, Kristen L.; Sevian, Hannah. J. Chem. Educ. 2006, 83, 1039.
Quantitative Analysis |
Green Chemistry |
Gravimetric Analysis |
Stoichiometry
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Microwave-Assisted Heterocyclic Chemistry for Undergraduate Organic Laboratory Robert Musiol, Bozena Tyman-Szram, and Jaroslaw Polanski Microwave-assisted techniques are used to design new environmentally benign syntheses of heterocycles for the undergraduate organic laboratory. Musiol, Robert; Tyman-Szram, Bozena; Polanski, Jaroslaw. J. Chem. Educ. 2006, 83, 632.
Green Chemistry |
Heterocycles |
Reactions |
Synthesis
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The Great Wakonse Earthquake of 2003: A Short, Problem-Based Introduction to the Titration Concept Brian P. Coppola, Amy C. Gottfried, Robyn L. Gdula, Alan L. Kiste, and Nathan W. Ockwig This activity introduces nonscience adult learners to the concept of titration from real-world instructions about earthquake water safety found in a California phone book. Coppola, Brian P.; Gottfried, Amy C.; Gdula, Robyn L.; Kiste, Alan L.; Ockwig, Nathan W. J. Chem. Educ. 2006, 83, 600.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
Qualitative Analysis |
Titration / Volumetric Analysis |
Water / Water Chemistry
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Teaching Chemistry Laboratory Skills in Industrial Contexts Julianne M. Braun and Carol White A recently completed project has produced a compilation of 40 laboratory experiments presented within the contexts of five major industries. This article provides a summary of these experiments, along with a discussion of ancillary materials. Braun, Julianne M.; White, Carol. J. Chem. Educ. 2006, 83, 353.
Applications of Chemistry |
Industrial Chemistry |
Metals |
Polymerization |
Water / Water Chemistry
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Linking Laboratory Experiences to the Real World: The Extraction of Octylphenoxyacetic Acid from Water Jorge E. Loyo-Rosales, Alba Torrents, Georgina C. Rosales-Rivera, and Clifford P. Rice A known quantity of the sodium salt of octylphenoxyacetic acid is dissolved in water, transformed to the acid (insoluble) form, and extracted using dichloromethane. These changes can be followed visually owing to conspicuous changes in solution turbidity. Loyo-Rosales, Jorge E.; Torrents, Alba; Rosales-Rivera, Georgina C.; Rice, Clifford P. J. Chem. Educ. 2006, 83, 248.
Acids / Bases |
Applications of Chemistry |
Aqueous Solution Chemistry |
pH |
Stoichiometry |
Nonmajor Courses |
Water / Water Chemistry
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An Interactive Environmental Science Course for Education Science Majors Suzanne K. Lunsford and William Slattery Describes an interactive environmental modular science course for education science majors preparing to become teachers at the primary and secondary levels. The purpose of the course is to give students experience in inquiry, gathering data, the evaluation of data to understand scientific theory, and the application of inquiry, hands-on methods in the classroom. Lunsford, Suzanne K.; Slattery, William. J. Chem. Educ. 2006, 83, 233.
Applications of Chemistry |
Geochemistry |
Nonmajor Courses |
Water / Water Chemistry |
Student-Centered Learning |
Standards National / State
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The Nature of Hydrogen Bonding Emeric Schultz Students use toy connecting blocks and Velcro to investigate weak intermolecular interactions, specifically hydrogen bonds. Schultz, Emeric. J. Chem. Educ. 2005, 82, 400A.
Noncovalent Interactions |
Hydrogen Bonding |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Covalent Bonding |
Molecular Modeling |
Molecular Properties / Structure
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Using Visible Spectrophotometers and pH Measurements To Study Speciation in a Guided-Inquiry Laboratory William H. Otto, Cynthia K. Larive, Susan L. Mason, Janet B. Robinson, Joseph A. Heppert, and James D. Ellis A collective-effort, guided-inquiry laboratory investigation was developed for the second-semester general chemistry laboratory for the purpose of increasing student conceptual understanding of equilibrium and speciation phenomena. This investigation required students to employ the chemical indicator phenol red in phosphate buffer solution, computer interfaced pH probes, and visible spectrophotometers. Through a combination of potentiometric and visible absorption measurements, the students determined the pH conditions that alter equilibrium concentrations of multiple species (colored and transparent) in solution. Otto, William H.; Larive, Cynthia K.; Mason, Susan L.; Robinson, Janet B.; Heppert, Joseph A.; Ellis, James D. J. Chem. Educ. 2005, 82, 1552.
Acids / Bases |
UV-Vis Spectroscopy |
Equilibrium |
pH |
Water / Water Chemistry |
Dyes / Pigments
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Sedimentation Time Measurements of Soil Particles by Light Scattering and Determination of Chromium, Lead, and Iron in Soil Samples via ICP Patricia Metthe Todebush and Franz M. Geiger In this two-part general chemistry laboratory activity, students study soil samples from home and from campus. In part one, the samples are placed in water and the suspended colloid fraction is separated using filtration, followed by a determination of colloid sedimentation rates via light scattering. In part two, the solid phase of the soil samples is dissolved in acid and analyzed for chromium, lead, and iron using an inductively coupled plasma spectrometer. The experiment can be expanded to include arsenic. Through these experiments students can draw conclusions about the physical and chemical behavior of solid components in soil, paying particular attention to their propensity for transporting and chemically transforming pollutants in the environment. Todebush, Patricia Metthe; Geiger, Franz M. J. Chem. Educ. 2005, 82, 1542.
Colloids |
Geochemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solids |
Surface Science |
Metals
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Equilibrium Constants and Water Activity David Keeports General chemistry instructors are faced with a dilemma when introducing the topic of equilibrium constants: These constants are correctly written in terms of activities, yet activity is a complex topic better treated rigorously in a physical chemistry course than superficially in a general chemistry course. Thus, to introduce equilibrium calculations, it is necessary to use approximate forms for equilibrium constants. However, I find that some commonly used textbooks provide incorrect arguments leading to approximate equilibrium constants for aqueous reactions. Keeports, David. J. Chem. Educ. 2005, 82, 999.
Acids / Bases |
Aqueous Solution Chemistry |
Equilibrium |
Water / Water Chemistry
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Conceptual Considerations in Molecular Science Donald T. Sawyer The undergraduate curriculum and associated textbooks include several significant misconceptions. Sawyer, Donald T. J. Chem. Educ. 2005, 82, 985.
Catalysis |
Covalent Bonding |
Electrolytic / Galvanic Cells / Potentials |
Oxidation / Reduction |
Reactions |
Reactive Intermediates |
Thermodynamics |
Water / Water Chemistry
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Going Green: Lecture Assignments and Lab Experiences for the College Curriculum Julie A. Haack, James E. Hutchison, Mary M. Kirchhoff, and Irvin J. Levy This paper provides an overview of green chemistry, including ways to incorporate green chemistry principles in existing courses and laboratories. Green chemistry experiments previously published in this Journal are listed. Haack, Julie A.; Hutchison, James E.; Kirchhoff, Mary M.; Levy, Irvin J. J. Chem. Educ. 2005, 82, 974.
Green Chemistry
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Thermal Expansion: Using Calculator-Based Laboratory Technology To Observe the Anomalous Behavior of Water Mario Branca and Isabella Soletta This is a simple experiment to observe variations in the density of water and other liquids at different temperatures with CBL technology. Using it students can observe the anomalous behavior of water at temperatures between 0 C and 4 C. Branca, Mario; Soletta, Isabella. J. Chem. Educ. 2005, 82, 613.
Liquids |
Physical Properties |
Water / Water Chemistry
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Simple Dynamic Models for Hydrogen Bonding Using Velcro-Polarized Molecular Models Emeric Schultz This article describes the use of models that dynamically illustrate the unique characteristics of weak intermolecular interactions, specifically hydrogen bonds. The models clearly demonstrate that H-bonds can break and reform while covalent bonds stay intact. The manner in which the models form and break H-bonds reflects the geometric and statistical manner in which H-bonding actually occurs and is not contrived. The use of these models addresses a significant area of student misconceptions. The construction of these molecular models is described. Schultz, Emeric. J. Chem. Educ. 2005, 82, 401.
Molecular Properties / Structure |
Molecular Modeling |
Noncovalent Interactions |
Hydrogen Bonding |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
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Hard Water and Soft Soap: Dependence of Soap Performance on Water Hardness. A Classroom Demonstration Viktoria K. L. Osorio, Wanda de Oliveira, and Omar A. El Seoud We describe a series of classroom demonstrations presented to high school students. The demonstrations were carried out to answer the question: Why does soap not foam in seawater? We generalized the question into: Why does soap performance depend on the hardness of the water used? A sequence of experiments was carried out to compare the performance of soap in soft and hard water and to illustrate the water-softening action of EDTA and zeolites. Osorio, Viktoria K. L.; de Oliveira, Wanda; El Seoud, Omar A. J. Chem. Educ. 2005, 82, 257.
Water / Water Chemistry |
Consumer Chemistry
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A Substitute for “Bromine in Carbon Tetrachloride” Joshua M. Daley and Robert G. Landolt Benzotrifluoride (BTF) is a suitable solvent substitute for carbon tetrachloride in experiments requiring application of bromine (Br2) in free radical or addition reactions with organic substrates. A 1 M solution of Br2 in BTF may be used to distinguish hydrocarbons based on the ease of abstraction of hydrogen atoms in thermally or light-induced free radical substitutions. Efficacy of minimization of solvent use, by aliquot addition to neat samples, has been established. Daley, Joshua M.; Landolt, Robert G. J. Chem. Educ. 2005, 82, 120.
Alkenes |
Free Radicals |
Green Chemistry |
Qualitative Analysis |
Reactions
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A Greener Approach for Measuring Colligative Properties Sean M. McCarthy and Scott W. Gordon-Wylie As a first step towards the greening of instructional laboratories, we present a new greener version of a laboratory procedure designed to measure colligative properties. The greener procedure substitutes the nontoxic, noncarcinogenic compounds stearic, myristic, lauric, and palmitic acids for the less benign aromatic compounds p-dichlorobenzene, benzil, biphenyl, naphthalene, and nitrotoluene. Achieving educational goals without the concomitant generation of chlorinated and aromatic wastes is shown here to be both possible and practical. McCarthy, Sean M.; Gordon-Wylie, Scott W. J. Chem. Educ. 2005, 82, 116.
Green Chemistry |
Solutions / Solvents |
Fatty Acids
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Capillary Electrophoresis Analysis of Cations in Water Samples. An Experiment for the Introductory Laboratory Christopher J. Pursell, Bert Chandler, and Michelle M. Bushey This experiment can be done in a lab, as a "dry-lab", or as an in-class exercise. Students explore a number of basic separation topics and work with figures of merit for real and meaningful samples. We have adopted a strategy where students encounter various instruments and methods of analyses multiple times throughout the curriculum. The level of sophistication in the exposures increases with the experience level of the students. Through this repeated exposure students will gain a better and fuller understanding of these methods than they would with a single exposure to the technique in the analytical or instrumental laboratory. Pursell, Christopher J.; Chandler, Bert; Bushey, Michelle M. J. Chem. Educ. 2004, 81, 1783.
Electrophoresis |
Quantitative Analysis |
Separation Science |
Chemometrics |
Water / Water Chemistry
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The Effect of Ionic Strength on the Solubility of an Electrolyte Joan D. Willey The theory of activity versus concentration is important in industrial, environmental, and biochemistry. The increase in solubility of an electrolyte in a solution of a second electrolyte with no common ions compared with pure water is not an easy concept to grasp because it seems to be counterintuitive. The simple experiment described here illustrates this principle visually and dramatically. Students attempt to dissolve CaSO42H2O (gypsum) in pure water and in 0.25 M NaCl. Willey, Joan D. J. Chem. Educ. 2004, 81, 1644.
Aqueous Solution Chemistry |
Quantitative Analysis |
Water / Water Chemistry |
Solutions / Solvents
|
Sink Inserts for Flood Prevention Fraser F. Fleming, Daniel J. Bodnar, and David L. Hardesty A simple, inexpensive insert is described for preventing flooding in lab sinks. The insert is essentially a tube with slots cut into the side that fits snugly into the drain outlet, preventing water buildup and providing additional drainage sites to avoid constriction by small lab items and paper towels. Fleming, Fraser F.; Bodnar, Daniel J.; Hardesty, David L. J. Chem. Educ. 2004, 81, 1344.
Laboratory Management |
Laboratory Equipment / Apparatus |
Water / Water Chemistry
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Water in the Atmosphere Joel M. Kauffman None of eight college-level general chemistry texts gave a mean value for water in the atmosphere, despite its being the third most prevalent constituent at about 1.5% by mass as vapor and about 2% if clouds and ice crystals are included. The importance of water as a greenhouse gas was omitted or marginalized by five of the eight texts. An infrared spectrum of humid air was determined to demonstrate that water vapor, because of its higher concentration, was more absorptive than carbon dioxide. The cooling effect of clouds, or other influences on the Earth's albedo, were not mentioned in most of the texts. These pervasive errors should be corrected in new or future editions of textbooks. Kauffman, Joel M. J. Chem. Educ. 2004, 81, 1229.
Atmospheric Chemistry |
Gases |
Green Chemistry |
IR Spectroscopy
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Introduction of Mass Spectrometry in a First-Semester General Chemistry Laboratory Course: Quantification of MTBE or DMSO in Water Mike Solow An experiment has been developed to introduce first-semester general chemistry students to mass spectrometry. Students analyze water samples contaminated with a known compound, either DMSO or MTBE. Students are asked to determine the concentration of the compound in the water. In performing this experiment, students should learn (i) how the mass of an atom or molecule is determined, (ii) the effect of the presence of different isotopes on molecular mass, (iii) the role of an internal standard, and (iv) how mass spectrometry is used in answering various scientific questions. Solow, Mike. J. Chem. Educ. 2004, 81, 1172.
Instrumental Methods |
Mass Spectrometry |
Quantitative Analysis |
Water / Water Chemistry |
Gas Chromatography
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Mass Spectrometry for the Masses Jared D. Persinger, Geoffrey C. Hoops, and Michael J. Samide In this article, we describe an experiment for an introductory chemistry course that incorporates the use of mass spectrometry for sample analysis. Several different air samples are collected that represent various chemical processes, and the composition of the air sample is predicted on the basis of known chemical principles. A gas chromatograph-mass spectrometer is used to analyze these samples, and the relative quantities of nitrogen, oxygen, carbon dioxide, water, and argon are calculated. On the basis of the data, the hypothesized sample composition is validated. Persinger, Jared D.; Hoops, Geoffrey C.; Samide, Michael J. J. Chem. Educ. 2004, 81, 1169.
Mass Spectrometry |
Atmospheric Chemistry |
Green Chemistry |
Nonmajor Courses |
Oxidation / Reduction |
Photosynthesis |
Gases
|
Kinetics of the Osmotic Hydration of Chickpeas Gabriel Pinto and Ali Esin An experiment examining the swelling of chickpeas as they are soaked in water is presented to introduce students to topics such as osmotic flow, mass transfer, diffusion, kinetics of hydration, modeling, and estimation of activation energy. Pinto, Gabriel; Esin, Ali. J. Chem. Educ. 2004, 81, 532.
Kinetics |
Water / Water Chemistry |
Food Science |
Transport Properties
|
Using Science Fiction To Teach Thermodynamics: Vonnegut, Ice-nine, and Global Warming Charles A. Liberko When covering the topic of thermodynamics at the introductory level, an example from Kurt Vonnegut, Jr's, fictional novel, Cat's Cradle, is used to take what the students have learned and apply it to a new situation. Liberko, Charles A. J. Chem. Educ. 2004, 81, 509.
Thermodynamics |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Noncovalent Interactions |
Calorimetry / Thermochemistry
|
A Modular Laser Apparatus for Polarimetry, Nephelometry, and Fluorimetry in General Chemistry Scott A. Darveau, Jessica Mueller, April Vaverka, Cheri Barta, Anthony Fitch, Jessica Jurzenski, and Yvonne Gindt We present an apparatus suitable for multiple uses in the general chemistry laboratory including polarimetry, fluorescence, and nephelometry. The open design of the instrument also decreases the chance that students will contract the "black-box syndrome" that seems to develop when using instruments that only provide the final data in an experiment without showing how the measurements are obtained. Darveau, Scott A.; Mueller, Jessica; Vaverka, April; Barta, Cheri; Fitch, Anthony; Jurzenski, Jessica; Gindt, Yvonne. J. Chem. Educ. 2004, 81, 401.
Fluorescence Spectroscopy |
Kinetics |
Laboratory Equipment / Apparatus |
Lasers |
Spectroscopy |
Proteins / Peptides |
Water / Water Chemistry
|
Magnetic Particle Technology. A Simple Preparation of Magnetic Composites for the Adsorption of Water Contaminants Luiz C. A. Oliveira, Rachel V. R. A. Rios, José D. Fabris, Rochel M. Lago, and Karim Sapag In this article a simple undergraduate laboratory experiment to produce magnetic adsorbents is described. These magnetic materials efficiently adsorb contaminants from water and can be easily removed from the medium by a simple magnetic separation process. Oliveira, Luiz C.A.; Rios, Rachel V.R.A.; Fabris, José D.; Lago, Rochel M.; Sapag, Karim. J. Chem. Educ. 2004, 81, 248.
Green Chemistry |
Magnetic Properties |
Materials Science |
Separation Science |
Water / Water Chemistry
|
Well Wishes. A Case on Septic Systems and Well Water Requiring In-Depth Analysis and Including Optional Laboratory Experiments Mary M. Walczak and Juliette M. Lantz This paper describes the use of a case study to teach introductory chemistry students the chemical principles of solution concentration (especially ppm) and dilution, aqueous redox reactions, and stoichiometric conversions between different solution species. Walczak, Mary M.; Lantz, Juliette M. J. Chem. Educ. 2004, 81, 218.
Consumer Chemistry |
Water / Water Chemistry |
Solutions / Solvents |
Oxidation / Reduction |
Stoichiometry
|
News from Online: Green Chemistry Erich S. Uffelman An introductory, non-exhaustive set of online resources is presented to provide readers with an entry into the area of green chemistry. Uffelman, Erich S. J. Chem. Educ. 2004, 81, 172.
Green Chemistry
|
Three-Dimensional Model for Water: Magnets as Dipoles Samuel H. Yalkowsky and Jennifer L. H. Johnson Reply to comments on original article. Yalkowsky, Samuel H.; Johnson, Jennifer L. H. J. Chem. Educ. 2004, 81, 34.
Aqueous Solution Chemistry |
Noncovalent Interactions |
Hydrogen Bonding |
Lipids |
Liquids |
Molecular Modeling |
Phases / Phase Transitions / Diagrams |
Solutions / Solvents |
Water / Water Chemistry
|
Three-Dimensional Model for Water: Magnets as Chemical Bonds Roy W. Clark Concerns over students confusing electrical and magnetic fields. Clark, Roy W. J. Chem. Educ. 2004, 81, 34.
Aqueous Solution Chemistry |
Noncovalent Interactions |
Hydrogen Bonding |
Lipids |
Liquids |
Molecular Modeling |
Phases / Phase Transitions / Diagrams |
Solutions / Solvents |
Water / Water Chemistry
|
Bubble Stripping To Determine Hydrogen Concentrations in Ground Water: A Practical Application of Henry's Law Daniel M. McInnes and Don Kampbell Applying Henry's law to determine the concentration of hydrogen in ground water as a means of identifying possible contamination by chlorinated organic compounds. McInnes, Daniel M.; Kampbell, Don. J. Chem. Educ. 2003, 80, 516.
Water / Water Chemistry |
Gases |
Quantitative Analysis |
Applications of Chemistry
|
Introduction to Green Chemistry (Mary Ann Ryan and Michael Tinnesand) Wheeler Conover Introduction to the principles of green chemistry emphasizing waste reduction; includes laboratory activities. Conover, Wheeler. J. Chem. Educ. 2003, 80, 268.
Green Chemistry |
Consumer Chemistry |
Applications of Chemistry
|
Micelle-Mediated Extraction of Heavy Metals from Environmental Samples: An Environmental Green Chemistry Laboratory Experiment Dimosthenis L. Giokas, Evangelos K. Paleologos, and Miltiades I. Karayannis A laboratory focussing on the determination of metallic elements in drinking water through cloud-point extraction. Giokas, Dimosthenis L.; Paleologos, Evangelos K.; Karayannis, Miltiades I. J. Chem. Educ. 2003, 80, 61.
Atomic Spectroscopy |
Metals |
Micelles |
Separation Science |
Green Chemistry |
Qualitative Analysis |
Quantitative Analysis
|
The Analysis of Seawater: A Laboratory-Centered Learning Project in General Chemistry Jodye I. Selco, Julian L. Roberts, Jr., and Daniel B. Wacks Experiment designed to introduce students to qualitative and quantitative analysis methods (gravimetric analysis, potentiometric titration, ion-selective electrodes, and atomic absorption and atomic emission spectroscopy) in the context of an overall analysis of an environmental sample. Selco, Jodye I.; Roberts, Julian L., Jr.; Wacks, Daniel B. J. Chem. Educ. 2003, 80, 54.
Aqueous Solution Chemistry |
Instrumental Methods |
Qualitative Analysis |
Quantitative Analysis |
Water / Water Chemistry |
Gravimetric Analysis |
Titration / Volumetric Analysis |
Ion Selective Electrodes |
Atomic Spectroscopy |
Potentiometry
|
Use of Chloroisocyanuarates for Disinfection of Water: Application of Miscellaneous General Chemistry Topics Gabriel Pinto and Brian Rohrig Using the chlorination of water (using sodium dichloroisocyanurate and trichloroisocyanuric acid) to develop general chemistry concepts; includes question for students and answers. Pinto, Gabriel; Rohrig, Brian. J. Chem. Educ. 2003, 80, 41.
Stoichiometry |
Water / Water Chemistry |
Applications of Chemistry |
Photochemistry
|
A Three-Dimensional Model for Water J. L. H. Johnson and S. H. Yalkowsky Using Molymod spheres and magnets to simulate the structure and properties of water and aqueous systems. Johnson, J. L. H.; Yalkowsky, S. H. J. Chem. Educ. 2002, 79, 1088.
Aqueous Solution Chemistry |
Covalent Bonding |
Lipids |
Liquids |
Solutions / Solvents |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
|
A Discovery-Based Experiment Illustrating How Iron Metal Is Used to Remediate Contaminated Groundwater Barbara A. Balko and Paul G. Tratnyek Procedure in which students investigate the chemistry of iron-permeable reactive barriers and their application to the remediation of contaminated groundwater. Balko, Barbara A.; Tratnyek, Paul G. J. Chem. Educ. 2001, 78, 1661.
Kinetics |
Oxidation / Reduction |
Water / Water Chemistry |
Metals |
Applications of Chemistry |
Aqueous Solution Chemistry
|
Humic Acids: Marvelous Products of Soil Chemistry Geoffrey Davies, Elham A. Ghabbour, and Cornelius Steelink Classification, physical and chemical characteristics, formation, structure and sources of humic substances. Davies, Geoffrey; Ghabbour, Elham A.; Steelink, Cornelius. J. Chem. Educ. 2001, 78, 1609.
Agricultural Chemistry |
Metals |
Natural Products |
Plant Chemistry |
Water / Water Chemistry |
Applications of Chemistry
|
Teaching Brønsted-Lowry Acid-Base Theory in a Direct Comprehensive Way Jamie L. Adcock Unifying all the Bronsted-Lowry acid-base concepts in a quantitative way. Adcock, Jamie L. J. Chem. Educ. 2001, 78, 1495.
Acids / Bases |
Equilibrium |
Learning Theories |
Water / Water Chemistry |
Brønsted-Lowry Acids / Bases
|
The Purification of Water by Freeze-Thaw or Zone Melting James Oughton, Silas Xu, and Rubin Battino Quantitative investigation of the purification of slat water solutions through the process of partial freezing. Oughton, James; Xu, Silas; Battino, Rubin. J. Chem. Educ. 2001, 78, 1373.
Conductivity |
Phases / Phase Transitions / Diagrams |
Separation Science |
Quantitative Analysis |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
|
A Microscale Spectrophotometric Determination of Water Hardness James S. Gordon Measuring water hardness using EDTA as a titrant, calmagite as an indicator, a colorimeter, and a graphing calculator. Gordon, James S. J. Chem. Educ. 2001, 78, 1089.
UV-Vis Spectroscopy |
Water / Water Chemistry |
Titration / Volumetric Analysis
|
Chemical Laboratory Information Profile: Water Jay A. Young Properties, hazards, and storage requirements for water. Young, Jay A. J. Chem. Educ. 2001, 78, 874.
Laboratory Management |
Physical Properties |
Water / Water Chemistry
|
Thermodynamics of Water Superheated in the Microwave Oven B. H. Erné Water is conveniently heated above its normal boiling point in a microwave oven in a glass microwave oven teapot. Water stops boiling soon after heating is interrupted, but subsequently added rough particles can still act as nucleation centers for a brief, spectacular burst of steam bubbles. The heat to make those steam bubbles obviously comes from the water itself, so that one can conclude that the boiling water was superheated, which is confirmed with a thermometer. Erné, B. H. J. Chem. Educ. 2000, 77, 1309.
Thermodynamics |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Liquids
|
Weak vs Strong Acids and Bases: The Football Analogy Todd P. Silverstein A football analogy for acids and bases in which acids are compared to quarterbacks, whose job is to get rid of the ball (H+). A strong acid, like an excellent quarterback, delivers the ball effectively; a weak acid, like a poor quarterback, is often left holding the ball. Furthermore, bases may be likened to wide receivers, whose job is to catch and hold onto the ball (H+). Silverstein, Todd P. J. Chem. Educ. 2000, 77, 849.
Acids / Bases |
Aqueous Solution Chemistry |
Water / Water Chemistry |
Brønsted-Lowry Acids / Bases
|
Microscale Chemistry and Green Chemistry: Complementary Pedagogies Mono M. Singh, Zvi Szafran, and R. M. Pike Green chemistry emphasizes the concepts of atom economy, source reduction, pathway modification, solvent substitution, and pollution prevention as means of improving the environmental impact of industrial chemistry. Microscale chemistry serves as a tool for incorporating green chemistry ideas across the curriculum in educational institutions. Examples are drawn from microscale laboratory experiments to illustrate the pedagogic connection between the two areas. Singh, Mono M.; Szafran, Zvi; Pike, Ronald M. J. Chem. Educ. 1999, 76, 1684.
Microscale Lab |
Learning Theories |
Green Chemistry |
Laboratory Management
|
Remediation of Water Contaminated with an Azo Dye: An Undergraduate Laboratory Experiment Utilizing an Inexpensive Photocatalytic Reactor John A. Bumpus, Jennifer Tricker, Ken Andrzejewski, Heather Rhoads, and Matthew Tatarko The construction and use of an inexpensive photocatalytic reactor that utilizes titanium dioxide as the photocatalyst for wastewater treatment is described. In these experiments and in supplementary material, students are made aware that a variety of techniques have been developed to treat wastewaters, including those generated by the chemical industry. Water contaminated with the azo dye Congo Red was selected as an example of how one might treat contaminated water from a textile manufacturing facility. Bumpus, John A.; Tricker, Jennifer; Andrzejewski, Ken; Rhoads, Heather; Tatarko, Matthew. J. Chem. Educ. 1999, 76, 1680.
Photochemistry |
Dyes / Pigments |
Laboratory Equipment / Apparatus |
Applications of Chemistry |
Water / Water Chemistry
|
Pesticides in Drinking Water: Project-Based Learning within the Introductory Chemistry Curriculum Patricia B. O'Hara, Jon A. Sanborn, and Meredith Howard A new introductory chemistry module is described, which has as its central theme the measurement of trace levels of these xenoestrogens in the form of pesticides in the Town of Amherst's public drinking water. After a basic introduction to sample handling and measurement of pH, temperature, and conductivity, the students travel in small groups to several sites to collect water and perform preliminary characterization of their samples. OHara, Patricia B.; Sanborn, Jon A.; Howard, Meredith. J. Chem. Educ. 1999, 76, 1673.
Mass Spectrometry |
Water / Water Chemistry |
Toxicology |
Applications of Chemistry
|
Learning Quality Assurance/Quality Control Using U.S. EPA Techniques. An Undergraduate Course for Environmental Chemistry Majors Susan M. Libes In the environmental realm, quality control (QC) includes activities associated with sampling, sample preservation and storage, method validation, and analysis involving solids, liquids, and gases. Students should be led to discover the need for QC by first performing analyses with little guidance. This is followed by a class discussion in which they critique their data. Libes, Susan. J. Chem. Educ. 1999, 76, 1642.
Instrumental Methods |
Quantitative Analysis |
Water / Water Chemistry
|
Bringing State-of-the-Art, Applied, Novel, Green Chemistry to the Classroom by Employing the Presidential Green Chemistry Challenge Awards Michael C. Cann In our environmental chemistry course at the University of Scranton, students select one of the winning entries from the most recent PGCC Awards competition and present a poster on the entry. This exercise exposes these students to state-of-the-art, applied, novel, green chemistry that they would be unlikely to encounter in any other course. Cann, Michael C. J. Chem. Educ. 1999, 76, 1639.
Learning Theories |
Green Chemistry
|
Using TOPEX Satellite El Niño Altimetry Data to Introduce Thermal Expansion and Heat Capacity Concepts in Chemistry Courses Harvey F. Blanck Warm water is less dense than cool water and will float somewhat like ice, with a portion above the surface of the cooler surrounding water. The height of the bump can be used to estimate the excess thermal energy in the warmer water. Blanck, Harvey F. J. Chem. Educ. 1999, 76, 1635.
Liquids |
Thermodynamics |
Water / Water Chemistry |
Calorimetry / Thermochemistry
|
The Softening of Hard Water and Complexometric Titrations: An Undergraduate Experiment Helena Ceretti, Enrique A. Hughes, and Anita Zalts An experiment in which (i) water hardness is explained and demonstrated; (ii) ion-exchange resin properties are visually demonstrated and then used for softening water; (iii) complexometric titrations are used for evaluating water hardness before and after softening; and (iv) acid-base titration can be used to show that the Ca/Mg ions removed by the ion exchanger are replaced by H ions. Ceretti, Helena; Hughes, Enrique A.; Zalts, Anita. J. Chem. Educ. 1999, 76, 1420.
Ion Exchange |
Quantitative Analysis |
Titration / Volumetric Analysis |
Water / Water Chemistry |
Acids / Bases
|
Experiments with Zeolites at the Secondary-School Level: Experience from The Netherlands Eric N. Coker, Pamela J. Davis, Aonne Kerkstra, and Herman van Bekkum This article describes a number of experiments that involve zeolites and are suitable for secondary-school chemistry laboratories. Students test the hardness of tap water before and after treatment with some zeolite and perform tests with a range of commercial laundry detergents containing zeolites. Coker, Eric N.; Davis, Pamela J.; Kerkstra, Aonne; van Bekkum, Herman. J. Chem. Educ. 1999, 76, 1417.
Ion Exchange |
Catalysis |
Quantitative Analysis |
Water / Water Chemistry |
Consumer Chemistry |
Applications of Chemistry
|
Cleaning Up with Chemistry: Investigating the Action of Zeolite in Laundry Detergent In this activity, you will investigate the properties of one ingredient, aluminosilicate. The particular aluminosilicate used in powdered laundry detergent is sodium zeolite A. In this activity, you will extract sodium zeolite A from powdered laundry detergent and examine its properties. J. Chem. Educ. 1999, 76, 1416A.
Materials Science |
Consumer Chemistry |
Applications of Chemistry |
Separation Science |
Water / Water Chemistry |
Ion Exchange
|
Relative Humidity R. Bruce Martin Daily we hear reports of relative humidity, yet most students remain unfamiliar with its import. This short article defines and describes the concept at several levels. A new, general interest, isobaric plot directly indicates the dependence of relative humidity on temperature. Martin, R. Bruce. J. Chem. Educ. 1999, 76, 1081.
Consumer Chemistry |
Gases |
Nonmajor Courses |
Water / Water Chemistry |
Atmospheric Chemistry
|
Predicting Acid-Base Titration Curves without Calculations Dennis W. Barnum In this paper a qualitative and systematic method for sketching titration curves is presented. Even the more complex cases such as salts or polyprotic acids and bases are treated just as easily as simple monoprotic acids. Having students predict the shape of titration curves from known equilibrium constants helps to focus attention on the general principles without distraction by the mathematics. Barnum, Dennis W. J. Chem. Educ. 1999, 76, 938.
Acids / Bases |
Quantitative Analysis |
Water / Water Chemistry |
Equilibrium |
Learning Theories |
Titration / Volumetric Analysis |
Chemometrics
|
The Chemistry of Water (by Susan E. Kegley and Joy Andrews) Debra J. McCool The Chemistry of Water is a super book. It is more than a textbook, more than a lab manual. There is a great amount of good chemistry packed into its 160 pages. This module looks at the purity of water and methods to assess water quality. McCool, Debra J. J. Chem. Educ. 1999, 76, 326.
Water / Water Chemistry
|
Spring Shock!: Impact of Spring Snowmelt on Lakes and Streams Judith A. Halstead This activity uses frozen vinegar to demonstrate that what melts first forms a liquid more concentrated in acetic acid than normal vinegar. As melting continues, the concentration of acetic acid decreases and the pH goes up. Judith A. Halstead. J. Chem. Educ. 1998, 75, 400A.
Acids / Bases |
Water / Water Chemistry
|
Identifying Bottled Water: A Problem-Solving Exercise in Chemical Identification Richard L. Myers Students are challenged to identify water samples using the known chemical analyses of bottled waters. Several common water quality measurements such as hardness, alkalinity, and ion analysis can be used by students to identify the unknown water. This exercise develops problem-solving skills as students become familiar with basic lab techniques, quality control, data interpretation, and standard methods. Myers, Richard L. J. Chem. Educ. 1998, 75, 1585.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Qualitative Analysis |
Consumer Chemistry
|
The Real Reason Why Oil and Water Don't Mix Todd P. Silverstein Authors should remove from their textbooks the incorrect enthalpic/hydrogen-bond explanation for the hydrophobic effect. Because aspects of the correct entropic/clathrate "cage" explanation lie beyond the scope of introductory or organic chemistry courses, it may be wisest to omit any detailed physical explanation of the "like dissolves like" phenomenon. Silverstein, Todd P. J. Chem. Educ. 1998, 75, 116.
Theoretical Chemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
|
The Source of the Cloud Produced upon Adding Dry Ice to Water Manu Kohli, Rudy L. Luck, and Veka Ohtamaa Explains why a cloud is produced by adding dry ice to water. Kohli, Manu; Luck, Rudy L.; Ohtamaa, Veka. J. Chem. Educ. 1998, 75, 60.
Solutions / Solvents |
Water / Water Chemistry
|
Acid Rain Demonstration: The Formation of Nitrogen Oxides as a By-Product of High-Temperature Flames in Connection with Internal Combustion Engines Jerry A. Driscoll This demonstration illustrates the formation of nitrogen oxides resulting from a high temperature flame. Driscoll, Jerry A. J. Chem. Educ. 1997, 74, 1424.
Equilibrium |
Learning Theories |
Water / Water Chemistry |
Oxidation / Reduction
|
Complexometric Titrations: Competition of Complexing Agents in the Determination of Water Hardness with EDTA M. Cecilia Yappert and Donald B. DuPre The competition of complexing agents for the same metal ion and the formation of colored metal-ion complexes is demonstrated with the use of an overhead projector. This demonstration can be used to emphasize both the relevance of the relative values of formation constants in the complexation of metal cations and the applicability of complexometric titrations in quantitative chemical analysis. Yappert, M. Cecilia; DuPre, Donald B. J. Chem. Educ. 1997, 74, 1422.
Equilibrium |
Coordination Compounds |
Qualitative Analysis |
Quantitative Analysis |
Titration / Volumetric Analysis |
Aqueous Solution Chemistry |
Water / Water Chemistry |
Metals
|
A Discussion of Water Pollution in the United States and Mexico; with High School Laboratory Activities for the Analysis of Lead, Atrazine, and Nitrate Paul B. Kelter, Julie Grundman, David S. Hage, James D. Carr, and Carlos Mauricio Castro-Acuña In the first part of this paper we present an overview of water pollution in the United States and Mexico, including sources, federal regulations and standards, and standard methods for the assessment of overall water quality. The second part of the paper focuses on three water pollutants, lead, atrazine, and nitrate. Kelter, Paul B.; Grundman, Julie; Hage, David S.; Carr, James D.; Mauricio, Carlos. J. Chem. Educ. 1997, 74, 1413.
Water / Water Chemistry
|
Integrating High School Chemistry with Environmental Studies and Research Jack Randall This article is a summary of a presentation made at the 1996 BCCE in Clemson, SC, as part of a symposium detailing the integration of environmental topics into Chemistry curricula. High school chemistry has long used environmental topics to enhance the study of various components of the curriculum. This article illustrates the benefits of incorporating environmental science as an integral part of a high school Chemistry course. Randall, Jack. J. Chem. Educ. 1997, 74, 1409.
Learning Theories |
Nonmajor Courses |
Water / Water Chemistry
|
News from Online Carolyn Sweeney Judd WWW sites related to water and related environmental issues. Judd, Carolyn Sweeney. J. Chem. Educ. 1997, 74, 1394.
Water / Water Chemistry
|
How to Offer the Optimal Demonstration of the Electrolysis of Water Rei E. Zhou This article proposes the optimal conditions for lecture demonstration to ensure that the generated H2 and O2 in the electrolysis of water are in the ratio of 2:1, satisfying the reaction scheme. Zhou, Rei E. J. Chem. Educ. 1996, 73, 786.
Water / Water Chemistry
|
Constant-Current Coulometric Titration of Hydrochloric Acid James Swim, Edward Earps, Laura M. Reed, and David Paul In this experiment we have combined the titration of a strong acid with a strong base and the electrolysis of water into one complete laboratory experience. James Swim, Edward Earps, Laura M. Reed, and David Paul. J. Chem. Educ. 1996, 73, 679.
Titration / Volumetric Analysis |
Acids / Bases |
Water / Water Chemistry |
Electrochemistry |
Oxidation / Reduction
|
Determination of Polychlorinated Biphenyls (PCBs) in River and Bay Sediments: An Undergraduate Laboratory Experiment in Environmental Chemistry Using Capillary Gas Chromatography with Electron Capture Detection Susan E. Kegley, Kristen J. Hansen, and Kevin L. Cunningham This paper briefly discusses the history of PCB use and provides guidelines for finding and evaluating PCB-contaminated sites as a way to interest students by showing them an application of chemistry to the "real world." Kegley, Susan E.; Hansen, Kristen J.; Cunningham, Kevin L. J. Chem. Educ. 1996, 73, 558.
Water / Water Chemistry |
Gas Chromatography |
Applications of Chemistry |
Separation Science |
Solutions / Solvents
|
The Bobbing (Drinking) Bird H. D. Gesser This article answers the question of when the bobbing bird will stop bobbing. It offers two scenarios in which the bird will discontinue its bobbing motion. Gesser, H. D. J. Chem. Educ. 1996, 73, 355.
Water / Water Chemistry
|
Crystallization of Supersaturated Sodium Acetate and the Temperature Dependence of the Autoionization Constant of Water Joseph A. Pergler, Ronald O. Ragsdale, and Thomas G. Richmond A procedure to qualitatively demonstrate the variation of the autoionization constant of water with temperature. Pergler, Joseph A.; Ragsdale, Ronald O.; Richmond, Thomas G. J. Chem. Educ. 1995, 72, 1027.
Crystals / Crystallography |
Aqueous Solution Chemistry |
Solutions / Solvents |
Acids / Bases |
Precipitation / Solubility |
Water / Water Chemistry
|
Introducing Green Chemistry in Teaching and Research Terrence J. Collins Efforts to integrate environmental considerations into the undergraduate chemistry curriculum and description of a course entitled "Introduction to Green Chemistry". Collins, Terrence J. J. Chem. Educ. 1995, 72, 965.
Green Chemistry
|
A New Low-Cost Apparatus for Electrolysis of Water Chieko Suzuki Low-cost alternative to the Hofmann apparatus for the electrolysis of water. Suzuki, Chieko. J. Chem. Educ. 1995, 72, 912.
Electrochemistry |
Water / Water Chemistry |
Laboratory Equipment / Apparatus
|
An Environmental Chemistry Curriculum Using Case Studies Cheng, Vincent K. W. Using case studies to make environmental chemistry more interesting and relevant for students. Cheng, Vincent K. W. J. Chem. Educ. 1995, 72, 525.
Water / Water Chemistry |
Industrial Chemistry
|
Lake Study for Macintosh Whisnant, David M.; McCormick, James; Wagner, Paul Software to simulate determination of the cause of fishkill in a lake. Whisnant, David M.; McCormick, James; Wagner, Paul J. Chem. Educ. 1995, 72, 492.
Water / Water Chemistry
|
Proper Waste Disposal Procedures (the author replies) Sherman, Marie C. Response to objections regarding improper waste disposal. Sherman, Marie C. J. Chem. Educ. 1995, 72, 286.
Water / Water Chemistry |
Laboratory Management
|
Proper Waste Disposal Procedures Clarke, Karl Objection to improper recommendation for waste disposal. Clarke, Karl J. Chem. Educ. 1995, 72, 286.
Water / Water Chemistry |
Laboratory Management
|
An Environmental Distillation Experiment for Nonscience Majors Soriano, David S.; Draeger, Jon A. Comparison of total dissolved solids for several samples of water before and after a single, simple distillation. Soriano, David S.; Draeger, Jon A. J. Chem. Educ. 1995, 72, 84.
Separation Science |
Water / Water Chemistry
|
Checking Trace Nitrate in Water and Soil Using an Amateur Scientist's Measurement Guide Baker, Roger C., Jr. Procedures and apparatus (photometer) for measuring concentrations of nitrates in water and soil using common equipment and materials; includes data and analysis. Baker, Roger C., Jr. J. Chem. Educ. 1995, 72, 57.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Agricultural Chemistry
|
Soda Water, Supercooling or Freezing Point Depression? Brooker, Murray H. Composition, preparation, properties, and behavior of soda water. Brooker, Murray H. J. Chem. Educ. 1994, 71, 903.
Gases |
Water / Water Chemistry |
Precipitation / Solubility |
Solutions / Solvents |
Consumer Chemistry
|
Testing the Waters for Chromium Herrmann, Mary S. A test for the presence of Cr(IV) in water using a sensitive colorimetric reagent. Herrmann, Mary S. J. Chem. Educ. 1994, 71, 323.
Water / Water Chemistry |
Metals |
Quantitative Analysis
|
A small-scale, easy-to-run wastewater-treatment plant: The treatment of an industrial water that contains suspended clays and soluble salts Alvaro, Mercedes; Espla, Mercedes; Llinares, Jesus; Martinez-Manez, Ramon; Soto, Juan Chemistry students are often interested in the chemical principles involved in industrial processes, the pollutants and waste products are generated, and their removal. This experiment introduces students to several theoretical concepts as they apply to real physical and chemical waste-treatment processes. Alvaro, Mercedes; Espla, Mercedes; Llinares, Jesus; Martinez-Manez, Ramon; Soto, Juan J. Chem. Educ. 1993, 70, A129.
Water / Water Chemistry |
Green Chemistry |
Industrial Chemistry |
Colloids |
Separation Science
|
Consequences of a chemical world: An innovative approach to teaching environmental chemistry Busch, Kenneth L.; Hughes, Kenneth D. A course that helps counteract chemophobia. Busch, Kenneth L.; Hughes, Kenneth D. J. Chem. Educ. 1993, 70, 1016.
Green Chemistry
|
Highlights: Ventures in freshman chemistry Farrar, James M.; Eisenberg, Richard; Kampmeier, J. A. A rigorous freshman chemistry course that prepares students for further study in chemistry and natural sciences ties principles of chemistry to energy and environment. Farrar, James M.; Eisenberg, Richard; Kampmeier, J. A. J. Chem. Educ. 1993, 70, 847.
Administrative Issues |
Green Chemistry |
Applications of Chemistry
|
A two-dimensional model for water Yalkowsky, Samuel H. The tetrahedral arrangement of the two hydrogen atoms and two electron pairs of the water molecule are difficult to represent diagrammatically in two dimensions, resulting in great difficulty to explain the anomalous properties of water. Nonetheless, the author illustrates the great insights that can be gained from two-dimensional analogies. Yalkowsky, Samuel H. J. Chem. Educ. 1993, 70, 614.
Water / Water Chemistry
|
Why is water blue? Braun, Charles L.; Smirnov, Sergei N. Exploring the problem of why water in a beaker appears to be clear, yet we see large bodies of water as blue in color. Braun, Charles L.; Smirnov, Sergei N. J. Chem. Educ. 1993, 70, 612.
Atomic Spectroscopy |
Water / Water Chemistry
|
A water treatment experiment (chemical hardness) for nonscience majors Soriano, David S.; Draeger, Jon A. Description of an activity used in a nonmajors course called 'Chemistry and Society'. Soriano, David S.; Draeger, Jon A. J. Chem. Educ. 1993, 70, 414.
Water / Water Chemistry |
Nonmajor Courses |
Instrumental Methods
|
Introducing the treatment of waste and wastewater in the general chemistry course: Applying physical and chemical principles to the problems of waste management Dhawale, S. W. Students learn simple lab techniques so that they can discuss applications such as cleanup of small-scale oil spills and the processes used to obtain drinkable pure water. Dhawale, S. W. J. Chem. Educ. 1993, 70, 395.
Water / Water Chemistry |
Green Chemistry |
Applications of Chemistry
|
Teaching risk assessment in undergraduate chemistry using BCTC Pharr, Daniel Y. 148. Bits and pieces, 49. The role of many scientists has become one of making policy decisions based on scientific data that is often incomplete and ambiguous. Having students go through the types of decisions that such scientists need to make by using the BCTC computer simulations can be a useful exercise to teach students how to research, collect, analyze, and interpret data. Pharr, Daniel Y. J. Chem. Educ. 1993, 70, 294.
Green Chemistry
|
Polarity, miscibility, and surface tension of liquids Silverstein, Todd P. A very simple overhead projector demonstration using water and ethanol to give a dramatic visual illustration of cohesive and adhesive forces. Silverstein, Todd P. J. Chem. Educ. 1993, 70, 253.
Water / Water Chemistry |
Solutions / Solvents
|
Lowering the surface tension of water: An illustration of the scientific method Jasien, Paul G.; Barnett, Glenn This demonstration has been effective in simulating a good discussion in class: floating non-wettable substances on the surface of water and touching the surface with a bar of soap. Jasien, Paul G.; Barnett, Glenn J. Chem. Educ. 1993, 70, 251.
Water / Water Chemistry
|
Interactive chemistry teaching units developed with the help of the local chemical industry: Applying classroom principles to the real needs of local companies to help students develop skill in teamwork, communications, and problem solving Pontin, J. A.; Arico, E.; Pitoscio Filho, J.; Tiedemann, P. W.; Isuyama, R.; Fettis, G. C. As part of a process of effective curriculum innovation, the authors are developing a project to produce teaching materials for chemistry undergraduate courses with an emphasis on the concerns of the local chemical industry. Pontin, J. A.; Arico, E.; Pitoscio Filho, J.; Tiedemann, P. W.; Isuyama, R.; Fettis, G. C. J. Chem. Educ. 1993, 70, 223.
Applications of Chemistry |
Green Chemistry |
Industrial Chemistry |
Student-Centered Learning
|
A Device to Collect Sediment Cores: And an Experiment for their Chemical Analysis Del Delumyea, R.; McCleary, Donna L. The chemical and physical characterization of sediments in aquatic systems can be performed at the introductory chemistry level and the experience is appealing and informative for students. This paper describes a device used to gather samples. Del Delumyea, R.; McCleary, Donna L. J. Chem. Educ. 1993, 70, 172.
Green Chemistry |
Laboratory Equipment / Apparatus
|
Environmental Chemistry in the Freshman Laboratory Kegley, Susan E.; Stacy, Angelica M. Lab activities related to environmental issues provide students with evidence of relevant chemistry while allowing students to engage in true inquiry experiences and engage themselves with challenging problems. Kegley, Susan E.; Stacy, Angelica M. J. Chem. Educ. 1993, 70, 151.
Green Chemistry |
Applications of Chemistry
|
Present and Future Nuclear Reactor Designs: Weighing the Advantages and Disadvantages of Nuclear Power with an Eye on Improving Safety and Meeting Future Needs Miller, Warren F., Jr. An overview of how nuclear energy is produced on macroscopic and microscopic scales with consideration given to benefits and liabilities of this energy source. The article includes a short look at nuclear power uses overseas and contains information about waste disposal, public opinion, and potential technical improvements. Miller, Warren F., Jr. J. Chem. Educ. 1993, 70, 109.
Nuclear / Radiochemistry |
Green Chemistry |
Consumer Chemistry |
Applications of Chemistry
|
The Erosion of Carbonate Stone by Acid Rain: Laboratory and Field Investigations Baedecker, Philip A.; Reddy, Michael M. Describes a laboratory experiment on the effects of acidic deposition on carbonate stone erosion. The purpose is to answer questions concerning the effects of hydrogen ion deposition on stone erosion processes that are difficult to resolve in field experiments alone. Baedecker, Philip A.; Reddy, Michael M. J. Chem. Educ. 1993, 70, 104.
Acids / Bases |
Green Chemistry
|
From Lead Solder to Kiwi Fruit: Reshaping Introductory Chemistry Labs with Investigative Team Projects Mahaffy, Peter G.; Newman, Kenneth E.; Bestman, Hank D. This paper reports an attempt to introduce relevant curriculum and investigations carried out by student research groups into a first year chemistry course. A description and evaluation of a four-week, open ended research project is included. Mahaffy, Peter G.; Newman, Kenneth E.; Bestman, Hank D. J. Chem. Educ. 1993, 70, 76.
Food Science |
Consumer Chemistry |
Laboratory Management |
Vitamins |
Green Chemistry |
Minorities in Chemistry
|
A Simple Demonstration of the Greenhouse Effect Adelhelm, Manfred; Hohn, Ernst-Gerhard A simple experiment to demonstrate the principle of the greenhouse effect. Adelhelm, Manfred; Hohn, Ernst-Gerhard J. Chem. Educ. 1993, 70, 73.
Photochemistry |
Green Chemistry
|
Microscale experiments: Dissolved oxygen and chloride determination in water Crosson, Mary; Gibb, Reen Determining the dissolved oxygen and chloride content of water samples through titrations. Crosson, Mary; Gibb, Reen J. Chem. Educ. 1992, 69, 830.
Microscale Lab |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Titration / Volumetric Analysis
|
Capillary radius and surface tensions: Using calculations based on Tate's law. Worley, John D. An experiment that can be carried out without the use of a tensiometer or any other complex or expensive apparatus except for a balance. Worley, John D. J. Chem. Educ. 1992, 69, 678.
Water / Water Chemistry |
Surface Science
|
The thermodynamics of home-made ice cream. Gibbon, Donald L.; Kennedy, Keith; Reading, Nathan; Quieroz, Mardsen. Using the production of ice cream to teach heat capacity, viscosity, and freezing-point reduction. Gibbon, Donald L.; Kennedy, Keith; Reading, Nathan; Quieroz, Mardsen. J. Chem. Educ. 1992, 69, 658.
Thermodynamics |
Water / Water Chemistry |
Applications of Chemistry
|
BCTC for Windows. Whisnant, David M.; McCormick, James. BCTC is an environmental simulation that is modeled after the dioxin controversy; students are involved in the investigation of a suspected carcinogen called BCTC found in a river and threatening a city's water supply. Whisnant, David M.; McCormick, James. J. Chem. Educ. 1992, 69, 638.
Water / Water Chemistry |
Toxicology
|
Simple soda bottle solubility and equilibria Snyder, Cheryl A.; Snyder, Dudley C. Using a bottle of selzter water and bromocresol green to demonstrate gas-liquid solubility (carbon dioxide in water). Snyder, Cheryl A.; Snyder, Dudley C. J. Chem. Educ. 1992, 69, 573.
Solutions / Solvents |
Precipitation / Solubility |
Equilibrium |
Gases |
Liquids |
Aqueous Solution Chemistry |
Water / Water Chemistry
|
A reasonable alternative to water aspiration Mulcahy, Francis M.; Robbins, Andrea M. The authors have designed a manifold system to obtain the greatest possible use of their vacuum pumps. Mulcahy, Francis M.; Robbins, Andrea M. J. Chem. Educ. 1992, 69, 428.
Laboratory Equipment / Apparatus |
Laboratory Management |
Water / Water Chemistry
|
Boiling and freezing simultaneously - with a feeble vacuum pump! Ellison, Mike The author uses this demonstration of freezing and boiling at reduced pressure to reinforce concepts about energy effects in phase changes. Ellison, Mike J. Chem. Educ. 1992, 69, 325.
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry |
Thermodynamics
|
Standard states for water equilibrium (author response). Campbell, Mark L.; Waite, Boyd A. For the purposes of comparison only the unconventionally derived Ka values should be used to compare equilibrium constants for other acids to determine relative acid strengths. Campbell, Mark L.; Waite, Boyd A. J. Chem. Educ. 1992, 69, 256.
Water / Water Chemistry |
Equilibrium |
Brønsted-Lowry Acids / Bases
|
Standard states for water equilibrium. Baldwin, W. George; Burchill, C. Eugene. The authors consider that Ka and Kb values for Bronsted acids and bases in aqueous solution represent one data set describing the properties of solutes in dilute aqueous solution. Baldwin, W. George; Burchill, C. Eugene. J. Chem. Educ. 1992, 69, 255.
Water / Water Chemistry |
Equilibrium |
Brønsted-Lowry Acids / Bases
|
Freezing point depression in a bottle of soda Bare, William D. The "ravenous consumption of soda" by today's students makes an interesting model with which to demonstrate the effect of solute concentration on the freezing point of an aqueous solution. Bare, William D. J. Chem. Educ. 1991, 68, 1038.
Aqueous Solution Chemistry |
Phases / Phase Transitions / Diagrams |
Water / Water Chemistry
|
Acid rain investigations Epp, Dianne N.; Curtright, Robert A series of reactions that can be carried out to demonstrate the effects of acid rain. Epp, Dianne N.; Curtright, Robert J. Chem. Educ. 1991, 68, 1034.
Acids / Bases |
Green Chemistry
|
Science and the environment: College undergraduates outreach to secondary schools Carlson, Nathan; Strickland, Tamara; Shen, Albert; Zoller, William H. An outreach program that generates concern and interest early in students' careers so that by the time they enter universities, they will have a clear picture of science as a rewarding career. Carlson, Nathan; Strickland, Tamara; Shen, Albert; Zoller, William H. J. Chem. Educ. 1991, 68, 1021.
Green Chemistry
|
Chemical equilibrium: VIII. Precipitates Gordus, Adon A. The final article in a series (see previous months this year): This article focuses on ionic precipitates in water and how buffered solutions allow easier calculation of solubilities. Gordus, Adon A. J. Chem. Educ. 1991, 68, 927.
Acids / Bases |
Equilibrium |
pH |
Precipitation / Solubility |
Aqueous Solution Chemistry |
Water / Water Chemistry
|
Demonstrations of interfacial phenomena Prall, Bruce R. Overhead projector demonstrations that illustrate the interfacial interactions of the following systems: 1) water and carbon tetrachloride, 2) copper wire and water, 3) 1-Octanol and water. Prall, Bruce R. J. Chem. Educ. 1991, 68, 592.
Surface Science |
Liquids |
Water / Water Chemistry |
Solutions / Solvents
|
Demonstration properties of sulfur dioxide Brouwer, H. Demonstrations of properties of sulfur dioxide are timely, given current debates between Canada and the United States regarding acid rain. Brouwer, H. J. Chem. Educ. 1991, 68, 417.
Acids / Bases |
Green Chemistry |
pH
|
Method for separating or identifying plastics Kolb, Kenneth E.; Kolb, Doris K. This article suggests the use of differences in density as a means for separation and identification of plastics. Kolb, Kenneth E.; Kolb, Doris K. J. Chem. Educ. 1991, 68, 348.
Consumer Chemistry |
Green Chemistry |
Physical Properties
|
Chloride in natural waters: An environmental application of a potentiometric titration Lisensky, George; Reynolds, Kelly. An environmental application of a potentiometric titration to determine chloride found in fresh water. Lisensky, George; Reynolds, Kelly. J. Chem. Educ. 1991, 68, 334.
Potentiometry |
Titration / Volumetric Analysis |
Green Chemistry |
Geochemistry |
Quantitative Analysis
|
Acid rain experiment and construction of a simple turbidity meter Betterton, Eric A. Construction of a simple turbidity meter in order to furnish more atmospheric chemistry experiments in the freshman and sophomore level chemistry lab. Betterton, Eric A. J. Chem. Educ. 1991, 68, 254.
Atmospheric Chemistry |
Laboratory Equipment / Apparatus |
Green Chemistry
|
Magnetic models of ions and water molecules for overhead projection Davies, William G. This paper describes a set of lecture-demonstration models that are easily made from ceramic magnets like those found in many discount stores and hobby shops. Davies, William G. J. Chem. Educ. 1991, 68, 245.
Water / Water Chemistry
|
Bromothymol surprise Maier, Linda L. Dropping a tablet of Alka Seltzer into a bromothymol blue solution. Maier, Linda L. J. Chem. Educ. 1990, 67, 963.
Acids / Bases |
Dyes / Pigments |
Aqueous Solution Chemistry |
Water / Water Chemistry
|
Ice under pressure Chang, Raymond; Skinner, James F. A piece of steel music wire pulled through a block of ice by weights on either side. Chang, Raymond; Skinner, James F. J. Chem. Educ. 1990, 67, 789.
Water / Water Chemistry |
Physical Properties
|
Recycling lead(II) halides from solubility experiments Scaife, Charles W.; Hall, Chadlee D. Procedure for recycling lead(II) chloride. Scaife, Charles W.; Hall, Chadlee D. J. Chem. Educ. 1990, 67, 605.
Green Chemistry |
Precipitation / Solubility
|
Magic sand: Modeling the hydrophobic effect and reversed-phase liquid chromatography Vitz, Ed The procedures described here are meant to reveal the important "nonsolvent" properties of water through its interaction with Magic Sand, and other synthetic silica derivatives. Vitz, Ed J. Chem. Educ. 1990, 67, 512.
Chromatography |
Water / Water Chemistry
|
An inexpensive device for collection of samples of water for dissolved oxygen determination without air contact Favaretto, Lelio This communication describes a simple and inexpensive device that permits the collection of water samples and fixation of dissolved oxygen by the Winkler method. Favaretto, Lelio J. Chem. Educ. 1990, 67, 509.
Water / Water Chemistry |
Laboratory Equipment / Apparatus
|
An inexpensive laboratory steam generator Hagen, James P.; Barton, Kevin L. The authors have devised an inexpensive, more efficient, safer heat source suitable for laboratories not equipped with house steam. Hagen, James P.; Barton, Kevin L. J. Chem. Educ. 1990, 67, 448.
Water / Water Chemistry |
Laboratory Equipment / Apparatus |
Laboratory Management
|
Dramatizing isotopes: Deuterated ice cubes sink Ellis, Arthur B.; Adler, Edward A.; Juergens, Frederick H. The authors describe a safe, striking demonstration of the effect of isotopic substitution. Ellis, Arthur B.; Adler, Edward A.; Juergens, Frederick H. J. Chem. Educ. 1990, 67, 159.
Water / Water Chemistry |
Isotopes
|
An automatic water trap for steam distillation Ruekberg, Ben The unpleasant aspects of the water trap can be avoided with a simple, inexpensive device that renders the water trap automatically selfdraining. Ruekberg, Ben J. Chem. Educ. 1990, 67, 66.
Separation Science |
Water / Water Chemistry |
Laboratory Equipment / Apparatus
|
An experiment to demonstrate the application of the scientific method Tannenbaum, Irving R. Boiling water as a demonstration to lead students to make and interpret careful observations. Tannenbaum, Irving R. J. Chem. Educ. 1989, 66, 597.
Water / Water Chemistry
|
Nuclear waste glass, and the Fe2+/Fe3+ ratio Fanning, James C.; Hunter, R. Todd These authors present a chemical problem of current interest that can be used for pedagogical purposes. Fanning, James C.; Hunter, R. Todd J. Chem. Educ. 1988, 65, 888.
Applications of Chemistry |
Consumer Chemistry |
Titration / Volumetric Analysis |
Oxidation State |
Nuclear / Radiochemistry |
Green Chemistry |
Chromatography |
Spectroscopy
|
The interconversion of electrical and chemical energy: The electrolysis of water and the hydrogen-oxygen fuel cell Roffia, Sergio; Concialini, Vittorio; Paradisi, Carmen Presentation of a simple apparatus that allows an instructor to perform the electrolysis of water and the back conversion of the products to water while overcoming some typical drawbacks encountered in this process. Roffia, Sergio; Concialini, Vittorio; Paradisi, Carmen J. Chem. Educ. 1988, 65, 725.
Water / Water Chemistry |
Electrochemistry
|
Interfacial phenomena Anwander, Alberto E.; Grant, Richard P. J. S.; Letcher, Trevor M. The interfaces between liquids, and liquids and gases, have a number of possible permutations that lead to exotic phenomenon such as antibubbles, floating drops, boules, polyaphrons, and hanging air bubbles. The authors give directions for demonstrating these in the classroom or lab. Anwander, Alberto E.; Grant, Richard P. J. S.; Letcher, Trevor M. J. Chem. Educ. 1988, 65, 608.
Surface Science |
Liquids |
Gases |
Physical Properties |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Phases / Phase Transitions / Diagrams
|
Let environmental chemistry enrich your curriculum Parravano, Carlo The rationale and detailed plans for a college level course in environmental chemistry. Parravano, Carlo J. Chem. Educ. 1988, 65, 235.
Green Chemistry |
Applications of Chemistry
|
A method for teaching science, technology, and societal issues in introductory high school and college chemistry classes Streitberger, H. Eric Most textbooks provide few, if any, systematic procedures for involving students with societal problems and issues in their lives related to chemistry. This is inconsistent with goals set in order to meet the growing need for students to be familiar with the science of (among other things) nutrition, environment, drugs, and more. This article gives a brief description of a project that acquaints students with these issues. Streitberger, H. Eric J. Chem. Educ. 1988, 65, 60.
Consumer Chemistry |
Industrial Chemistry |
Green Chemistry |
Nuclear / Radiochemistry
|
Correct equilibrium constants for water (the authors reply) Starkey, Ronald; Norman, Jack; Hinitze, Mark Water and hydronium ion Ka values are special cases. Starkey, Ronald; Norman, Jack; Hinitze, Mark J. Chem. Educ. 1987, 64, 1068.
Equilibrium |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Acids / Bases |
Thermodynamics
|
Correct equilibrium constants for water Baldwin, W. George; Burchill, C. Eugene Disagreement with the numerical values assigned to equilibrium constants. Baldwin, W. George; Burchill, C. Eugene J. Chem. Educ. 1987, 64, 1067.
Equilibrium |
Water / Water Chemistry |
Acids / Bases |
Aqueous Solution Chemistry
|
When oil and water do not mix Trammell, Gary L. An introduction to the physics and chemistry of interfaces and lipids, and reactions in micelles. Trammell, Gary L. J. Chem. Educ. 1987, 64, 1022.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Solutions / Solvents |
Micelles |
Lipids
|
An aqueous problem with an interesting solution Thomas, Nicholas C. Flow diagram outlining the steps to calculating the number of water molecules in one drop of water and the length of all these molecules stretched end to end. Thomas, Nicholas C. J. Chem. Educ. 1987, 64, 611.
Water / Water Chemistry |
Stoichiometry
|
The energy relationships of corn production and alcohol fermentation Van Koevering, Thomas E.; Morgan, Michael D.; Younk, Thomas J. The production of alcohol from corn lends itself well to illustrating the practical applications of scientific principles that deal with energy transformations and inefficiencies. Van Koevering, Thomas E.; Morgan, Michael D.; Younk, Thomas J. J. Chem. Educ. 1987, 64, 11.
Natural Products |
Applications of Chemistry |
Plant Chemistry |
Green Chemistry |
Alcohols |
Calorimetry / Thermochemistry |
Photosynthesis
|
The quicker picker upper experiment Snow, Albert J. A popular commercial slogan as an in for chemistry instructors to talk about capillary action. Snow, Albert J. J. Chem. Educ. 1986, 63, 1086.
Applications of Chemistry |
Consumer Chemistry |
Water / Water Chemistry
|
The electrolysis of water: An improved demonstration procedure Heideman, Stephen The usual use of sulfuric acid as the electrolyte in the demonstration of the electrolysis of water does not allow students to observe the accompanying pH changes at the electrodes. Heideman, Stephen J. Chem. Educ. 1986, 63, 809.
Water / Water Chemistry |
pH |
Electrochemistry
|
The water softener - A relevant, unifying example of many common chemical principles and calculations Fulkrod, John E. Determining the amount of sodium chloride needed for a water softener to replace all the hard water ions in a month's water supply for a typical household. Fulkrod, John E. J. Chem. Educ. 1985, 62, 529.
Applications of Chemistry |
Water / Water Chemistry |
Aqueous Solution Chemistry
|
Water electrolysis-A surprising experiment Kelsh, Dennis J. Using aluminum wire for the cathode will produce "too much" hydrogen. Kelsh, Dennis J. J. Chem. Educ. 1985, 62, 154.
Water / Water Chemistry |
Electrochemistry
|
The effect of polarity on solubility Nordstrom, Brian H. Students observe that iodine dissolves readily in 1,1,1-trichloroethane but not water. Nordstrom, Brian H. J. Chem. Educ. 1984, 61, 1009.
Precipitation / Solubility |
Solutions / Solvents |
Molecular Properties / Structure |
Water / Water Chemistry
|
Modeling hypersaline lake "turn-over" Sprague, Gary Modeling saline lake inversions with a saturated salt solution in a beaker. Sprague, Gary J. Chem. Educ. 1984, 61, 956.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Solutions / Solvents
|
Scientific exploration with a microcomputer: Simulations for nonscientists Whisnant, David M. 52. A four week-long exercise aimed at involving students with the scientific method through the use of a computer-simulated lake study. Whisnant, David M. J. Chem. Educ. 1984, 61, 627.
Nonmajor Courses |
Water / Water Chemistry |
Applications of Chemistry
|
Oil shale - Heir to the petroleum kingdom Schachter, Y. A discussion of oil shale provides students with real-world problems that require chemical literacy. Schachter, Y. J. Chem. Educ. 1983, 60, 750.
Applications of Chemistry |
Alkenes |
Alkanes / Cycloalkanes |
Green Chemistry
|
A quantitative gas chromatographic ethanol determination: a contemporary analytical experiment Leary, James J. This note describes a gas chromatographic experiment for the quantitative determination of volume percent ethanol in water ethanol solutions. Leary, James J. J. Chem. Educ. 1983, 60, 675.
Gas Chromatography |
Quantitative Analysis |
Water / Water Chemistry |
Alcohols
|
Estimating energy outputs of fuels Baird, N. Colin Which is the best fuel in terms of heat energy output: coal, natural gas, fuel oil, hydrogen, or alcohol? It is possible to obtain a semi quantitative estimate of the heat generated by combustion of a fuel from the balanced chemical equation alone. Baird, N. Colin J. Chem. Educ. 1983, 60, 356.
Reactions |
Green Chemistry |
Thermodynamics |
Alcohols |
Alkanes / Cycloalkanes |
Geochemistry |
Stoichiometry |
Quantitative Analysis
|
Encapsulation of organic chemicals within starch matrix: an undergraduate laboratory experiment Wing, R. E.; Shasha, B. S. This experiment explores current environmentally friendly technology. Wing, R. E.; Shasha, B. S. J. Chem. Educ. 1983, 60, 247.
Green Chemistry |
Applications of Chemistry |
Agricultural Chemistry
|
The determination of anionic surfactants in natural and waste waters Crisp, P. T.; Eckert, J. M.; Gibson, N. A. The experiment described in this paper is suitable for the measurement of subpart per million concentrations of anionic surfactants in natural waters and industrial effluents. Crisp, P. T.; Eckert, J. M.; Gibson, N. A. J. Chem. Educ. 1983, 60, 236.
Industrial Chemistry |
Water / Water Chemistry |
Surface Science
|
The chemical oceanographer Abel, Robert B. Oceanography holds fascinating subject matter for students learning chemistry. Abel, Robert B. J. Chem. Educ. 1983, 60, 221.
Water / Water Chemistry |
Food Science |
Geochemistry |
Atmospheric Chemistry |
Drugs / Pharmaceuticals |
Applications of Chemistry
|
Simple control system for automated, multistage stills Uphaus, R. A.; Kostka, A. G. A system that uses LEDs to sense the water level in a still pot and control the rate of heat input to the still heating jackets. Uphaus, R. A.; Kostka, A. G. J. Chem. Educ. 1982, 59, 674.
Laboratory Equipment / Apparatus |
Water / Water Chemistry
|
A simple experiment for determining vapor pressure and enthalpy of vaporization of water Levinson, Gerald S. It is possible to determine the vapor pressure of water using only a tall beaker, a graduated cylinder, and a thermometer. Levinson, Gerald S. J. Chem. Educ. 1982, 59, 337.
Water / Water Chemistry |
Gases |
Phases / Phase Transitions / Diagrams
|
Red cabbage and the electrolysis of water Skinner, James F. The demonstration profiled here has proven effective in bringing together concepts from acid-base chemistry and electrochemistry. Skinner, James F. J. Chem. Educ. 1981, 58, 1017.
Electrochemistry |
Water / Water Chemistry |
Acids / Bases
|
Red cabbage and the electrolysis of water Skinner, James F. The demonstration profiled here has proven effective in bringing together concepts from acid-base chemistry and electrochemistry. Skinner, James F. J. Chem. Educ. 1981, 58, 1017.
Electrochemistry |
Water / Water Chemistry |
Acids / Bases
|
A novel source of distilled water for science laboratories in the humid tropics Ikediobi, C. O. One of the most serious infrastructure headaches of developing countries is the acute shortage of potable water. In the face of this difficulty, the author offers some helpful tips for chemistry instructors. Ikediobi, C. O. J. Chem. Educ. 1981, 58, 788.
Water / Water Chemistry |
Laboratory Management
|
Stormy weather Taylor, Thomas E. Question regarding the formation of rain clouds and the exothermic process of condensation. Taylor, Thomas E. J. Chem. Educ. 1980, 57, 732.
Thermodynamics |
Atmospheric Chemistry |
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams
|
Fluoridated water Muhler, Joseph C. Answers to a number of questions regarding the fluoridation of drinking water. Muhler, Joseph C. J. Chem. Educ. 1980, 57, 496.
Applications of Chemistry |
Aqueous Solution Chemistry |
Water / Water Chemistry
|
Wonder water: Another idea that is hard to work into a conversation Smith, Douglas D. The many benefits of degassed water. Smith, Douglas D. J. Chem. Educ. 1979, 56, 338.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Applications of Chemistry
|
Development of intellectual skills in the laboratory Ophardt, Charles E. This first semester laboratory was designed to give instruction and practice in the intellectual skills of application, analysis, synthesis, and in Piaget's formal operations. Ophardt, Charles E. J. Chem. Educ. 1978, 55, 485.
Learning Theories |
Qualitative Analysis |
Water / Water Chemistry |
Atmospheric Chemistry |
Acids / Bases |
Titration / Volumetric Analysis
|
Solar energy concepts in the teaching of chemistry Cantrell, Joseph S. A justification for why solar energy concepts should be included in the teaching of chemistry and some curricular tips for the integration of these concepts. Cantrell, Joseph S. J. Chem. Educ. 1978, 55, 41.
Green Chemistry
|
Emphasis on acids and bases J. Chem. Educ. Staff Considers the acidity or basicity in soils and natural waters; the acid-base balance in body chemistry; acidic and basic foods; the approximate pH values of common fluids; examples of acidic, basic, and neutral drugs; and the commercial preparation of nitric acid. J. Chem. Educ. Staff J. Chem. Educ. 1977, 54, 626.
Acids / Bases |
Water / Water Chemistry |
Food Science |
Applications of Chemistry |
pH |
Drugs / Pharmaceuticals
|
Questions [and] Answers Campbell, J. A. 323-329. Campbell, J. A. J. Chem. Educ. 1977, 54, 622.
Enrichment / Review Materials |
Water / Water Chemistry |
Toxicology |
Applications of Chemistry
|
Questions [and] Answers Campbell, J. A. 315-322. Eight questions on subjects related to environmental chemistry and their answers. Campbell, J. A. J. Chem. Educ. 1977, 54, 498.
Enrichment / Review Materials |
Applications of Chemistry |
Water / Water Chemistry |
Atmospheric Chemistry
|
Silver ion in water purification: A follow-up Quane, Denis Applying a previous idea on the possible use of silver ion in water purification to teaching the concept of Ksp. Quane, Denis J. Chem. Educ. 1977, 54, 381.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Equilibrium |
Solutions / Solvents
|
Le Chtelier's principle: A laboratory exercise Friedman, Frederica Le Chtelier's principle can be demonstrated by showing that water can boil at temperatures below 100C due to reduced vapor pressure. Friedman, Frederica J. Chem. Educ. 1977, 54, 236.
Equilibrium |
Phases / Phase Transitions / Diagrams |
Gases |
Water / Water Chemistry
|
Chemist's view of oceanography Cutshall, Norman H. The structure of oceanography, chemists in oceanography, chemical analysis in oceanography, chemical oceanography research, and chemical oceanographers in marine pollution studies. Cutshall, Norman H. J. Chem. Educ. 1977, 54, 162.
Applications of Chemistry |
Aqueous Solution Chemistry |
Water / Water Chemistry
|
Marine biochemistry. A new interdisciplinary course for the interim Goldberg, Arthur S. A course was implemented entitled "Marine Biochemistry" as a result of both student interest and increasing awareness of scientists of the potential usefulness of substances from the sea. A number of recent books and articles have been published and used as source material for the course. Goldberg, Arthur S. J. Chem. Educ. 1976, 53, 717.
Water / Water Chemistry
|
Separation of waste plastics. An experiment in solvent fractionation Seymour, Raymond B.; Stahl, G. Allan The authors share their design for a scheme for separation of specific plastics from a mixture. This activity engages students and relates to recycling. Seymour, Raymond B.; Stahl, G. Allan J. Chem. Educ. 1976, 53, 653.
Green Chemistry |
Separation Science |
Applications of Chemistry
|
Non-covalent interactions: Key to biological flexibility and specificity Frieden, Earl Summarizes the types of non-covalent interactions found among biomolecules and how they facilitate the function of antibodies, hormones, and hemoglobin. Frieden, Earl J. Chem. Educ. 1975, 52, 754.
Noncovalent Interactions |
Hydrogen Bonding |
Water / Water Chemistry |
Proteins / Peptides |
Amino Acids |
Molecular Properties / Structure |
Hormones
|
Chlorine in your water Smith, J. G. The use, chemistry, and alternatives to chlorine and chlorine compounds in water supplies. Smith, J. G. J. Chem. Educ. 1975, 52, 656.
Water / Water Chemistry |
Consumer Chemistry
|
Questions [and] Answers Campbell, J. A. 206-211. Six questions regarding topics in environmental chemistry and biochemistry. Campbell, J. A. J. Chem. Educ. 1975, 52, 655.
Enrichment / Review Materials |
Applications of Chemistry |
Water / Water Chemistry
|
Questions [and] Answers Campbell, J. A. 193-197. Five biochemical questions and their answers. Campbell, J. A. J. Chem. Educ. 1975, 52, 457.
Enrichment / Review Materials |
pH |
Isotopes |
Water / Water Chemistry
|
The energy crisis. A new chemistry course for nonscience majors Piraino, Marie J. After years of having had taught traditional chemistry courses for nonscience majors, the author shifted her curriculum toward developing an understanding of political, economic, and health issues affecting contemporary students. Piraino, Marie J. J. Chem. Educ. 1974, 51, 802.
Nonmajor Courses |
Applications of Chemistry |
Green Chemistry
|
A study of water pollution. An undergraduate chemistry laboratory experience Sarkis, Vahak D. In addition to its environmental relevance, a water pollution study of the inorganic constituents in water as outlined in this article, provides the student with certain important principles of chemistry namely, colorimetric and titrimetric procedures. Sarkis, Vahak D. J. Chem. Educ. 1974, 51, 745.
Applications of Chemistry |
Metals |
Green Chemistry |
Water / Water Chemistry |
Titration / Volumetric Analysis
|
Analysis of chlorinated hydrocarbon pesticides. Experiments for nonscience majors Glover, Irving T.; Minter, Ann P. This experiment allows students to explore the chemistry behind a controversial concern. Glover, Irving T.; Minter, Ann P. J. Chem. Educ. 1974, 51, 685.
Green Chemistry |
Toxicology |
Applications of Chemistry
|
Demonstration of solubility of "immiscible" fluids Koob, R. D.; Tallman, D. E. Demonstrating that hexane is miscible in water. Koob, R. D.; Tallman, D. E. J. Chem. Educ. 1973, 50, 724.
Solutions / Solvents |
Precipitation / Solubility |
Water / Water Chemistry |
Alkanes / Cycloalkanes
|
Nitric acid in rain water Gleason, Geoffrey I. This trace analysis experiment is based on the conversion of nitrate to nitrite using a cadmium amalgam reductor column. Gleason, Geoffrey I. J. Chem. Educ. 1973, 50, 718.
Acids / Bases |
Water / Water Chemistry |
Atmospheric Chemistry
|
The chemistry of pollution - An experimental course Frank, David L. Briefly outlines the goals and topics of a course entitled "Chemistry of Air Pollution." Frank, David L. J. Chem. Educ. 1973, 50, 209.
Atmospheric Chemistry |
Water / Water Chemistry
|
Dissolved oxygen determination Berger, Toby E. Details regarding the cited procedure. Berger, Toby E. J. Chem. Educ. 1973, 50, 160.
Water / Water Chemistry |
Solutions / Solvents
|
Notes on determination of dissolved oxygen Sommers, Raymond A. Simplifications in the referenced procedure that make it more suitable for the introductory laboratory. Sommers, Raymond A. J. Chem. Educ. 1973, 50, 160.
Water / Water Chemistry |
Solutions / Solvents
|
Special session: Women's caucus Brownlee, Paula
Brownlee, Paula J. Chem. Educ. 1973, 50, 21.
Conferences |
Professional Development |
Water / Water Chemistry
|
Beyond the Conventional Classroom. Session II-A: Continuing education Heikkinen, Henry; Zuehlke, Rick; Alexander, John Combating technical obsolescence; rent o prof; water, man and chemistry; and an undergraduate-graduate research collaboration program. Heikkinen, Henry; Zuehlke, Rick; Alexander, John J. Chem. Educ. 1973, 50, 18.
Conferences |
Professional Development |
Industrial Chemistry |
Water / Water Chemistry |
Undergraduate Research
|
The determination of dissolved oxygen by the Winkler method. A student laboratory experiment McCormick, Patrick G. This method is based on the reaction between oxygen and a suspension of manganese(II) hydroxide in a strongly alkaline solution. McCormick, Patrick G. J. Chem. Educ. 1972, 49, 839.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Gases |
Quantitative Analysis |
Titration / Volumetric Analysis
|
Radiometric analysis of ammonia in water Mehra, M. C. In this experiment, the silver concentration in aqueous solution is determined radiometrically using silver-110 as the radiotracer. Mehra, M. C. J. Chem. Educ. 1972, 49, 837.
Water / Water Chemistry |
Nuclear / Radiochemistry |
Isotopes |
Aqueous Solution Chemistry |
Quantitative Analysis
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Sliding friction and skiing Plumb, Robert C.; Van Hook, Alexander What causes the film of water to form under skis and ice skates? Plumb, Robert C.; Van Hook, Alexander J. Chem. Educ. 1972, 49, 830.
Water / Water Chemistry
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Water analysis experiment Anderlick, Barbara Analyzing various water samples for the presence of a variety of ions. Anderlick, Barbara J. Chem. Educ. 1972, 49, 749.
Water / Water Chemistry |
Qualitative Analysis |
Aqueous Solution Chemistry |
Metals
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Efficient use of washing solvents. A quantitative treatment Boschmann, Edwin A quantitative study of the efficient use of washing solvents (e.g. distilled water) in the laboratory. Boschmann, Edwin J. Chem. Educ. 1972, 49, 650.
Laboratory Management |
Water / Water Chemistry
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Measurement of pH of distilled water Youmans, Hubert L. Resolving the problem of pH meters giving readings for the pH of distilled water that differ significantly from 7. Youmans, Hubert L. J. Chem. Educ. 1972, 49, 429.
Water / Water Chemistry |
pH |
Quantitative Analysis
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Dissolved oxygen. A relevant experiment for the introductory laboratory Stagg, William R. Students measure the dissolved oxygen content of water from several natural sources as well as the change in solubility with temperature. Stagg, William R. J. Chem. Educ. 1972, 49, 427.
Water / Water Chemistry |
Oxidation / Reduction |
Quantitative Analysis |
Solutions / Solvents |
Precipitation / Solubility |
Gases
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Why is the oxygen in water negative? Liebman, Joel F. Oxygen in water is negative because a negative charge, unlike a positive, can be stabilized using ground state ionic resonance structures. Liebman, Joel F. J. Chem. Educ. 1972, 49, 415.
Water / Water Chemistry |
Molecular Properties / Structure |
Oxidation State
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Chemistry laboratories and other ecosystems Wynn, Charles M. Suggestions for reducing water pollution from the chemistry laboratory. Wynn, Charles M. J. Chem. Educ. 1972, 49, 225.
Laboratory Management |
Water / Water Chemistry
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Squeak, skid and glide - The unusual properties of snow and ice Plumb, Robert C.; Fletcher, N. H. The Clapeyron equation controls the behavior of ice under varying conditions of temperature and pressure. Plumb, Robert C.; Fletcher, N. H. J. Chem. Educ. 1972, 49, 179.
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Equilibrium
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Squeak, skid and glide - The unusual properties of snow and ice Plumb, Robert C.; Fletcher, N. H. The Clapeyron equation controls the behavior of ice under varying conditions of temperature and pressure. Plumb, Robert C.; Fletcher, N. H. J. Chem. Educ. 1972, 49, 179.
Water / Water Chemistry |
Phases / Phase Transitions / Diagrams |
Equilibrium
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The effervescence of ocean surf Plumb, Robert C.; Blanchard, Duncan C.; Bilofsky, Howard S.; Bridgman, Wilbur B. A pure liquid will not foam, but all true solutions will, as dictated by the fundamental concepts of surface thermodynamics enunciated by Gibbs. Plumb, Robert C.; Blanchard, Duncan C.; Bilofsky, Howard S.; Bridgman, Wilbur B. J. Chem. Educ. 1972, 49, 29.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Gases |
Solutions / Solvents |
Thermodynamics
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An introductory experiment on phosphates in detergents Mohrig, Jerry R. Examines the phosphate controversy, the roles of phosphates in detergents, the chemistry of phosphates and their colorimetric determination, and presents an experiment in which the amount of phosphate is measured using two different analytical methods. Mohrig, Jerry R. J. Chem. Educ. 1972, 49, 15.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Consumer Chemistry |
Quantitative Analysis |
Applications of Chemistry
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Polywater. A lesson and opportunity in science Christian, P. A.; Berka, L. H. The authors present an intriguing observation and offer outlines of some possible studies that can be undertaken in any adequately equipped high school or college chemistry laboratory. Christian, P. A.; Berka, L. H. J. Chem. Educ. 1971, 48, 667.
Water / Water Chemistry |
Solutions / Solvents
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Analysis of phosphate in detergents Kriz, George S., Jr.; Kriz, Kay Dian The experiment described here is a response to the need mentioned above and is specifically concerned with water pollution caused by phosphate detergents. It is ideal for today's students who concerned about the environment. Kriz, George S., Jr.; Kriz, Kay Dian J. Chem. Educ. 1971, 48, 551.
Surface Science |
Water / Water Chemistry |
Applications of Chemistry
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Heat of hydration Dannhauser, Walter A commonly published experiment can be expanded so that students may obtain the enthalpy of the reaction between anhydrous salts and water. Dannhauser, Walter J. Chem. Educ. 1971, 48, 329.
Thermodynamics |
Crystals / Crystallography |
Water / Water Chemistry |
Noncovalent Interactions
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Is ammonia like water? Gill, J. B. This article sets out to compare some of the properties of the two most widely studied solvents, water and liquid ammonia, and in particular illustrate some comparative aspects that are not normally considered. Gill, J. B. J. Chem. Educ. 1970, 47, 619.
Water / Water Chemistry |
Molecular Properties / Structure |
Aqueous Solution Chemistry
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Calcium carbonate equilibria in the oceans - ion pair formation Morton, Stephen D.; Lee, G. Fred Discusses some of the problems encountered in studying the chemistry of lakes and oceans, focussing on the solubility of calcium carbonate in marine environments. Morton, Stephen D.; Lee, G. Fred J. Chem. Educ. 1968, 45, 513.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Precipitation / Solubility |
Qualitative Analysis
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Calcium carbonate equilibria in lakes Morton, Stephen D.; Lee, G. Fred Discusses some of the problems encountered in studying the chemistry of lakes and oceans, focussing on the solubility of calcium carbonate in fresh water lakes. Morton, Stephen D.; Lee, G. Fred J. Chem. Educ. 1968, 45, 511.
Aqueous Solution Chemistry |
Water / Water Chemistry |
Precipitation / Solubility |
Equilibrium
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Group 1. The Alkali Metals. The Copper Group Mancuso, Carl J.; Alyea, Hubert N. Demonstrations include the density and melting point of copper versus sodium, the conductivity of sodium, the reactivity with water of groups IA vs IB, and the stability of CO3--, HCO3-, and hydroxides of groups IA vs IB. Mancuso, Carl J.; Alyea, Hubert N. J. Chem. Educ. 1967, 44, A919.
Metals |
Reactions |
Water / Water Chemistry |
Aqueous Solution Chemistry |
Physical Properties
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Electrolysis: H2O and H2O2 Eberhardt, William H. This demonstration involves the concurrent electrolysis of water and hydrogen peroxide. Eberhardt, William H. J. Chem. Educ. 1964, 41, A591.
Electrochemistry |
Water / Water Chemistry
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A model of the ice structure Lambert, Jack L.; Seitz, Larry M. Instructions for constructing a physical model of ice. Lambert, Jack L.; Seitz, Larry M. J. Chem. Educ. 1964, 41, 504.
Water / Water Chemistry |
Molecular Modeling |
Molecular Properties / Structure
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Distilled water purity monitor using an ac polarization electrode Freedman, R. W.; Radkoff, S. Presents a circuit diagram for a distilled water purity monitor using an ac polarization electrode. Freedman, R. W.; Radkoff, S. J. Chem. Educ. 1964, 41, 387.
Water / Water Chemistry |
Laboratory Equipment / Apparatus
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Removal of hardness and deionization of water by the ion exchange method Sangster, A. W. Demonstrates the removal of calcium and chloride ions through ion exchange. Sangster, A. W. J. Chem. Educ. 1963, 40, A987.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Ion Exchange
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The hydrated hydronium ion Clever, H. Lawrence It is the purpose of this brief review to cite and discuss some of the evidence for the existence of the trihydrated hydronium ion. Clever, H. Lawrence J. Chem. Educ. 1963, 40, 637.
Water / Water Chemistry |
Aqueous Solution Chemistry |
Acids / Bases |
Brønsted-Lowry Acids / Bases
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Alkali metal-water reactions Markowitz, Meyer M. The typical open-air demonstration of sodium reacting with water does not in reality represent the typical reaction of an alkali metal with liquid water; the article goes on to consider other factors that may influence these reactions. Markowitz, Meyer M. J. Chem. Educ. 1963, 40, 633.
Reactions |
Metals |
Water / Water Chemistry
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The science study series. Volumes 12 and 18 Kieffer, William F.
Kieffer, William F. J. Chem. Educ. 1961, 38, 588.
Atomic Properties / Structure |
Nuclear / Radiochemistry |
Water / Water Chemistry
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Ultra Low Conductivity Water National Bureau of Standards Summary Technical Report Describes the production of water with a conductivity approaching the lower theoretical limit. National Bureau of Standards Summary Technical Report J. Chem. Educ. 1961, 38, 421.
Water / Water Chemistry |
Conductivity |
Aqueous Solution Chemistry
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The ionization constant of water Dirkse, Thedford P. Some textbooks claim that the ion product constant of water is constant under all conditions at a given temperature. Dirkse, Thedford P. J. Chem. Educ. 1961, 38, 260.
Water / Water Chemistry |
Aqueous Solution Chemistry
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Effect of water on the interaction of aluminum and iodine Azmatullah, Syed; Viswanathan, Argot A drop of water added to powdered aluminum and iodine initiates a vigorous reaction. Azmatullah, Syed; Viswanathan, Argot J. Chem. Educ. 1955, 32, 447.
Water / Water Chemistry |
Reactions
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Water, a basic natural resource Keirstead, Ralph E. Describes the many uses for water and its importance as a basic natural resource. Keirstead, Ralph E. J. Chem. Educ. 1955, 32, 99.
Water / Water Chemistry
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