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Metal Complexes of Trifluoropentanedione. An Experiment for the General Chemistry LaboratoryRobert C. Sadoski, David Shipp, and Bill Durham Investigation of the transition-metal complexes produced by the reactions of Cr(III), Mn(II), Fe(III), Co(II), Ni(II), and Cu(II) with 1,1,1-trifluoro-2,4-pentanedione; mass spectroscopy is used to determine the stoichiometry of the reaction products. Sadoski, Robert C.; Shipp, David; Durham, Bill. J. Chem. Educ.2001, 78, 665.
Coordination Compounds |
Synthesis |
Mass Spectrometry |
Transition Elements |
Stoichiometry
Fast and slow reactions of chromium compoundsKnox, Kerro The inertness of ligand substitution by chromium(III) ions is compared with other reactions that do proceed at reasonably fast rates, and an outcome is obtained in which two solutions of identical compositions contain different chromium species of different colors. Knox, Kerro J. Chem. Educ.1990, 67, 700.
Coordination Compounds |
Transition Elements
Density gradient columns for chemical displaysGuenther, William B. An important advantage of these demonstrations of complex chemistry is that students can observe them over a period of time as they grasp concepts of solution equilibria. Guenther, William B. J. Chem. Educ.1986, 63, 148.
