21.5. Bonding in Complex Ions: The Localized Electron Model
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The Electrochemical Synthesis of Transition-Metal AcetylacetonatesS. R. Long, S. R. Browning, and J. J. Lagowski The electrochemical synthesis of transition-metal acetylacetonates can assist in the transformation of an entry-level laboratory course into a research-like environment where all members of a class are working on the same problem, but each student has a personal responsibility for the synthesis and characterization of a specific compound. Long, S. R.; Browning, S. R.; Lagowski, J. J. J. Chem. Educ.2008, 85, 1429.
Coordination Compounds |
Electrochemistry |
IR Spectroscopy |
Physical Properties |
Synthesis |
Transition Elements |
UV-Vis Spectroscopy
Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) ComplexesRichard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction. Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ.2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
Prussian Blue: Artists' Pigment and Chemists' SpongeMike Ware The variable composition of Prussian blue tantalized chemists until investigations by X-ray crystallography in the late 20th century explained its many properties and uses. Ware, Mike. J. Chem. Educ.2008, 85, 612.
Werner and Jørgensen Bond TheoryDavid M. Whisnant, Laura Yindra This simulation begins in the period around 1870 when chemistry is beginning to be organized. The concept, introduced by Kekulé and Couper, of tetravalent carbon atoms capable of linking to each other has permitted the rise of structural concepts in organic chemistry.
Nomenclature / Units / Symbols |
Valence Bond Theory
The Evolution of Bond TheoryDavid M. Whisnant, Laura Yindra In chemistry lectures we have little time to discuss the history of chemistry. This simulation begins with the development of valence concepts in the 19th century. We will step back into the 19th century to see how theories of chemical combination changed during that time.
Nomenclature / Units / Symbols |
Valence Bond Theory
Coordination CompoundsEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.