| Other Resources: 52 results |
The Nobel Prize and Aqua Regia Robert Hetue A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Aqueous Solution Chemistry |
Precipitation / Solubility
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Ionic Equilibria in Aqueous Solutions in Foods Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Nutrition |
Aqueous Solution Chemistry
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Calcium tartrate and treatment of wine waste-waters Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Equilibrium
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The Solubility Product Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Equilibrium
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Introduction of Aquatic Chemistry in General Chemistry Curriculum;Spreadsheet Calculation Approaches Chulsung Kim Fundamental aquatic chemistry concepts may be introduced in general chemistry classes by computing ionization fractions and buffer intensity of aqueous phase carbonate systems. This Excel spreadsheet may used to build graphic presentations of a titration curve, distribution diagram, and buffer intensity as a function of pH. Accompanying activities are designed to enhance the concepts of acid-base equilibrium through exploring the relationship between pKa/pKb, pH of the solution, ionization fractions, and buffer intensity, and to exercise students graphing skills.
Acids / Bases |
Aqueous Solution Chemistry |
pH |
Titration / Volumetric Analysis |
Water / Water Chemistry |
Equilibrium
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Computer Simulations of Salt Solubility Victor M. S. Gil, João C. M. Paiva Computer Simulations of Salt Solubility provides an animated, visual interpretation of the different solubilities of related salts based on simple entropy changes associated with dissolution: configurational disorder and thermal disorder. This animation can also help improve students conceptual understanding of chemical equilibrium before any quantitative interpretation of equilibrium constants is attempted.
Computational Chemistry |
Solutions / Solvents |
Thermodynamics |
Equilibrium |
Precipitation / Solubility
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Molecular Models of EDTA and Other Chelating Agents William F. Coleman Deirdre Bell-Oudry presents a variation on an old theme in her paper on using an indirect EDTA titration for sulfate analysis (1). EDTA and (often loosely) related species are this month's Featured Molecules.EDTA is a hexaprotic acid (H6Y2+) having the pKa values given in the featured paper (1). Figure 1 shows a distribution diagram for the EDTA system (2). At the pH of normal waters, the predominant species have one or both of the nitrogen atoms protonated.Complexation, however, requires that both nitrogens be deprotonated and it is generally assumed that the form that complexes with metal ions is Y4−. Structures of several forms of EDTA are included in the molecule collection (Figure 2). These structures are quite flexible having many conformations that are readily accessible at room temperature.An introduction to EDTA chemistry leads to broader questions of metal ion chelation or sequestration. Related chelating agents included in the molecule collection are EGTA, DCTA, NTA, BAPTA, and DTPA. Molecular dynamics and Hartree-Fock calculations on BAPTA (Figure 2) confirm that many conformations, ranging from those with the phenyl rings parallel to one another, to more elongated forms, are essentially isoenergetic in room temperature aqueous solution (3).Also included in the molecule collection are several crown ethers, an isophore (nonactin), and a cryptand. These not only provide students with a glimpse of the types of molecules being employed for metal ion sequestration but open a wide range of topics of current research in a variety of areas of inorganic, industrial, environmental, and biological chemistry.
Aqueous Solution Chemistry
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Hydration of Ions Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Aqueous Solution Chemistry
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Conjugate Acid-Base Pairs and pH Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Aqueous Solution Chemistry
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Ammonia (GCMP) David M. Whisnant Ammonia fountain: this is a resource in the collection "General Chemistry Multimedia Problems". In an ammonia fountain, a flask is filled with ammonia gas. A tube from the flask extends into a pan of water that contains phenolphthalein. When a rubber bulb full of water is squeezed, the water squirts into the flask. Water from the pan then is pushed into the flask and the indicator changes color. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Acids / Bases |
Aqueous Solution Chemistry
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Buffer Solutions Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Acids / Bases |
Aqueous Solution Chemistry
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Solubility and Molecular Structure Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility
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Solubility and Molecular Structure in the Environment Sarah Yue A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility
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The Common-Ion Effect Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility
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The Solubilities of Salts of Weak Acids Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility
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Hydrogen and Hydroxide Ions Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Aqueous Solution Chemistry |
Water / Water Chemistry
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Saturated and Supersaturated Solutions Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Solutions / Solvents |
Precipitation / Solubility
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Miscibility Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Liquids
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Ksp and calcium fortification Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Nutrition
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Solubility of calcium salts in foods Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Nutrition
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Low solubility salts in dairy products - Calcium phosphate and lactate Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Precipitation / Solubility |
Nutrition
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Nitrogen Oxides (GCMP) David M. Whisnant Nitrogen Oxides: this is a resource in the collection "General Chemistry Multimedia Problems". Two of the most important nitrogen oxides, N2O4 and NO2, are in equilibrium with each other. We are interested in how this equilibrium shifts with temperature. General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Equilibrium
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How Accurate Is the Steady State Approximation Lars Ole Haustedt, Jonathan M. Goodman The steady-state approximation is commonly used in enzyme catalysis kinetics calculations, but how much error does the approximation introduce? This Java applet allows you to visually determine the accuracy of the steady-state and pre-equilibrium approximations.
Equilibrium
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ChemPaths 104 W Mar 2 John W. Moore Today in Chem 104:
* Lecture: Chemical Equilibrium
* Reading:
Kotz: Ch. 16, Sec. 1-2
Moore: Ch. 14, Sec. 1-2
* Homework #6 due by 11:55 pm F Mar 4
* Quiz #4 given in second discussion section this week
* Biomolecules Tutorial: Enzymes and Moodle Quiz due Today at 11:55 pm
Equilibrium
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ChemPaths 104 F Mar 4 John W. Moore Today in Chem 104:
* Lecture: Problem-Solving Session
* No assigned reading for today.
* Homework #6 due by 11:55 pm Today!
Equilibrium
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ChemPaths 104 M Mar 7 John W. Moore Today in Chem 104:
* Lecture: Chemical Equilibrium
* Reading:
Kotz: Ch. 16, Sec. 3-5
Moore: Ch. 14, Sec. 3-5
* Homework #7 due by 11:55 pm F Mar 11
* Quiz #5 given in second discussion section this week.
Equilibrium
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ChemPaths 104 W Mar 9 John W. Moore Today in Chem 104:
* Lecture: Chemical Equilibrium
* Reading:
Kotz: Ch. 16, Sec.6
Moore: Ch. 14, Sec. 6, 8
* Homework #7 due by 11:55 pm F Mar 11
* Quiz #5 given in second discussion section this week.
Equilibrium
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ChemPaths 104 F Mar 11 John W. Moore Today in Chem 104:
* Lecture: Problem-Solving Session
* No assigned reading for today.
* Homework #7 due by 11:55 pm Today!
Equilibrium
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Equilibrium Constants Revisited Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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The Equilibrium State Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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The Equilibrium Constant Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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The Law of Chemical Equilibrium Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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Calculating the Extent of a Reaction Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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Successive Approximation Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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Effect of Adding a Reactant or Product Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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The Molecular View of Equilibrium Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium
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Contrail. A Module from the Physical Chemistry On-Line Project Franklin M. C. Chen The condensation trail, or contrail, that trails behind a jet plane is an everyday observable phenomenon. These manmade cirrus clouds can persist for hours, or even days and can spread over thousands of square kilometers. This is a concern because clouds are major variables that control Earth's atmospheric temperature and climate. Understanding the impact of contrails on Earth's climate is an active area of research. Further, contrail formation can be examined in terms of the operative thermodynamic phenomena. The process of contrail formation involves combustion, cooling, and ice formation, all common topics in the undergraduate physical chemistry curriculum. The project when it is subdivided into separate manageable subjects is a good, comprehensive exercise for physical chemistry students.
Thermodynamics |
Equilibrium
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Predicting the Direction of a Reaction Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Thermodynamics
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Le Chatelier's Principle Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Reactions |
Equilibrium
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The Effect of a Change in Pressure Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Reactions |
Equilibrium
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Buffer solutions and the stability of food additives Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Acids / Bases |
Equilibrium |
Nutrition
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Buffer solutions and the production of food ingredients Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Acids / Bases |
Equilibrium |
Nutrition
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The effect of polyols on the pH of buffer solutions in foods Sofia Erazo A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Acids / Bases |
Equilibrium |
Nutrition
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ChemPaths 104 M Apr 11 John W. Moore Today in Chem 104:
* Lecture: pH; Acid-Base Equilibria; Ionization
* Reading:
Kotz: Ch. 17, Sec. 6-7
Moore: Ch. 16, Sec. 7-8
* Homework #10 due by 11:55 PM F Apr 15
* Quiz in second discussion section this week
* Lab this week is #6, Acid and Base Solutions
pH |
Acids / Bases |
Equilibrium
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The Equilibrium Constant in Terms of Pressure Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Physical Properties
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The pH of Solutions of Weak Acids Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Acids / Bases
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The pH of Solutions of Weak Bases Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Acids / Bases
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Vapor-Liquid Equilibrium Ed Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Equilibrium |
Phases / Phase Transitions / Diagrams
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Equilibrium Matthew Sandberg, Mike Bellamy Using a visual approach, this applet is designed to help students learn to solve equilibrium calculations and also to help them gain a deeper understanding of the topic. It can be used by the instructor in the classroom as equilibrium topics are introduced. Sample exercises for students are included. The text is available in both English and Spanish.
Chemometrics |
Equilibrium |
Enrichment / Review Materials
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JavaScript Programs To Calculate Thermodynamic Properties Using Cubic Equations of State Patrick J. Barrie Cubic equations of state are widely used by chemists and chemical engineers to predict the thermodynamic properties of both pure substances and mixtures. In particular, these equations enable predictions concerning the temperature and pressure at which vapor liquid equilibrium occurs. These two educational JavaScript programs perform calculations using cubic equations of state and, equally importantly, explain how the calculations are performed.
Mathematics / Symbolic Mathematics |
Chemometrics |
Thermodynamics |
Equilibrium |
Enrichment / Review Materials
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Connected Chemistry Mike Stieff Connected Chemistry, a novel learning environment for teaching chemistry, is appropriate for use in both high school and undergraduate chemistry classrooms. Connected Chemistry comprises several molecular simulations designed to enable instructors to teach chemistry using the perspective of emergent phenomena. That is, it allows students to see observed macro-level chemical phenomena, like many other scientific phenomena, as resultant from the interactions of many individual agents on a micro-level. This perspective is especially appropriate to the study of chemistry where the interactions between multitudes of molecules on the atomic level give rise to the macro-level concepts that students study in the classroom. Connected Chemistry comprises molecular simulations embedded in the NetLogo modeling software (1). The collection contains several predesigned simulations of closed chemical systems to teach specific chemistry concepts. Currently, Connected Chemistry contains models for teaching Brønsted Lowry acid base theory, enzyme kinetics, radical polymerization, buffer chemistry, kinetics, chemical equilibrium, and crystallization. Instructors and students can individually tailor the predesigned simulations or generate new simulations as they are needed in the context of a particular lesson, classroom, or department.
Acids / Bases |
Gases |
Kinetics |
Nuclear / Radiochemistry |
pH |
Titration / Volumetric Analysis |
Polymerization |
Equilibrium |
Catalysis
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General Chemistry Multimedia Problems David M. Whisnant General Chemistry Multimedia Problems ask students questions about experiments they see presented using videos and images. The questions asked apply concepts from different parts of an introductory course, encouraging students to decompartmentalize the material.
Acids / Bases |
Atomic Spectroscopy |
Calorimetry / Thermochemistry |
Isotopes |
Magnetic Properties |
Phases / Phase Transitions / Diagrams |
Surface Science |
Thermodynamics |
Equilibrium |
Oxidation / Reduction
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