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The Nernst Equation: Determination of Equilibrium Constants for Complex Ions of SilverMartin L. Thompson and Laura J. Kateley The experiment requires a voltmeter capable of recording millivolts (or a good pH meter) and inexpensive chemicals. It allows students to check the validity of the Nernst equation and compare their experimental Kform values to reported ones. Thompson, Martin L.; Kateley, Laura J. J. Chem. Educ.1999, 76, 95.
Equilibrium |
Coordination Compounds |
Electrochemistry |
Oxidation / Reduction
Acid-Base Chemistry of the Aluminum Ion in Aqueous SolutionEdward Koubek A demonstration of the amphoteric behavior of aluminum is given based on an older report that was given many years ago. Koubek, Edward. J. Chem. Educ.1998, 75, 60.
Coordination Compounds |
Equilibrium |
Acids / Bases |
Aqueous Solution Chemistry
Complexometric Titrations: Competition of Complexing Agents in the Determination of Water Hardness with EDTAM. Cecilia Yappert and Donald B. DuPre The competition of complexing agents for the same metal ion and the formation of colored metal-ion complexes is demonstrated with the use of an overhead projector. This demonstration can be used to emphasize both the relevance of the relative values of formation constants in the complexation of metal cations and the applicability of complexometric titrations in quantitative chemical analysis. Yappert, M. Cecilia; DuPre, Donald B. J. Chem. Educ.1997, 74, 1422.