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Kinetics : RateLawChangeConc (10 Variations) The rate law for a reaction is rate=k[A][B]. If the concentration of A doubles, the rate of the reaction will do which of the following?
Kinetics : RxnOrder (10 Variations)
For the reaction below, determine the order with respect to each reactant and the overall order.
2NO2(g) + F2(g) 2NO2F(g)
rate = k[NO2][F2]
Data Pooling in a Chemical Kinetics Experiment: The Aquation of a Series of Cobalt(III) ComplexesRichard S. Herrick, Kenneth V. Mills, and Lisa P. Nestor Describes an experiment that introduces students to integrated rate laws, the search for a mechanism that is consistent with chemical and kinetic data, and the concept of activation barriers and their measurement in a curriculum whose pedagogical philosophy makes the laboratory the center of learning for undergraduates in their first two years of instruction. Herrick, Richard S.; Mills, Kenneth V.; Nestor, Lisa P. J. Chem. Educ.2008, 85, 1120.
Coordination Compounds |
Kinetics |
Mechanisms of Reactions |
Rate Law |
UV-Vis Spectroscopy
Reaction Order Ambiguity in Integrated Rate PlotsJoe Lee This article provides a theoretical and statistical justification for the necessity of monitoring a reaction to a substantial fraction of completion if integrated rate plots plots are to yield unambiguous orders. Lee, Joe. J. Chem. Educ.2008, 85, 141.
Chemometrics |
Kinetics |
Rate Law
Visualizing the Transition State: A Hands-on Approach to the Arrhenius EquationThomas S. Kuntzleman, Matthew S. Swanson, and Deborah K. Sayers Pennies and dice are used to simulate the kinetics of two irreversible "reactions" with a hands-on, Monte Carlo approach. Arrhenius plots of the data generated yield activation energies comparable to assigned values and pre-exponential factors close to what would be expected based on the probability of a "reactant" achieving the correct orientation for conversion into "product". A comparison of the values obtained for the pre-exponential factors for the different simulations allows students to semi-quantitatively discuss the orientational requirement that is contained within this factor. Kuntzleman, Thomas S.; Swanson, Matthew S.; Sayers, Deborah K. J. Chem. Educ.2007, 84, 1776.
ChemPaths 104 M Feb 21John W. Moore Today in Chem 104:
* Lecture: Rate Laws
* Reading:
Kotz:, Ch. 15, Sec. 3-4
Moore, Ch. 13, Sec. 3-5
* Homework #5 due by 11:55 pm F Feb 25
* Excel assignment due in first discussion section this week
* Quiz 4 in second discussoin section
Kinetics |
Rate Law
The Rate EquationEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
Kinetics |
Rate Law
Unimolecular ProcessesEd Vitz, John W. Moore A section of ChemPrime, the Chemical Educations Digital Library's free General Chemistry textbook.
2NO2F(g)
